huagongshe.com
结构：CC(C)OC(=O)/N=N/C(=O)OC(C)C
HCID5363146

Diisopropyl azodicarboxylate

propan-2-yl (NE)-N-propan-2-yloxycarbonyliminocarbamate

C8H14N2O4202.21 g/molCAS 2446-83-5
查看相关反应子结构检索查找相似结构

IDENTITY

结构与身份

标准 SMILES
CC(C)OC(=O)/N=N/C(=O)OC(C)C
InChIKey
VVWRJUBEIPHGQF-MDZDMXLPSA-N
分子式
C8H14N2O4
平均分子量
202.21 g/mol
单同位素质量
202.09535693

COMPUTED

结构计算性质

已同步
XLogP
2.6
极性表面积
77.3 Ų
氢键供体
0
氢键受体
4
可旋转键
4
重原子
14
形式电荷
0
复杂度
211

PROPERTIES

实验与物化性质

来源：PubChem
Physical Description

Orange liquid; [Merck Index] Pungent odor; [Alfa Aesar MSDS]

GHS

GHS 分类

来源：PubChem
GHS Classification

This chemical does not meet GHS hazard criteria for 35.9% (52 of 145) of reports.

Warning

H315 (62.8%): Causes skin irritation [Warning Skin corrosion/irritation]；H319 (62.8%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]；H335 (61.4%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]；H373 (54.5%): May causes damage to organs through prolonged or repeated exposure [Warning Specific target organ toxicity, repeated exposure]；H411 (61.4%): Toxic to aquatic life with long lasting effects [Hazardous to the aquatic environment, long-term hazard]

P260, P261, P264, P264+P265, P271, P273, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P391, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 145 reports by companies from 21 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Reported as not meeting GHS hazard criteria per 52 of 145 reports by companies.；There are 20 notifications provided by 93 of 145 reports by companies with hazard statement code(s).；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

HAZARDS

危害信息

来源：PubChem
Regulatory Information

Status: Active Update: 02-11-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/23916

Diisopropylazodicarboxylate: Does not have an individual approval but may be used under an appropriate group standard

Hazards Summary

A skin, respiratory tract, and strong eye irritant; [Alfa Aesar MSDS] See Diethyl azodicarboxylate.

Hazard Classes and Categories

Skin Irrit. 2 (62.8%)；Eye Irrit. 2 (62.8%)；STOT SE 3 (61.4%)；STOT RE 2 (54.5%)；Aquatic Chronic 2 (61.4%)

REGULATORY

法规信息

来源：PubChem
Regulatory Information

Status: Active Update: 02-11-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/23916

Diisopropylazodicarboxylate: Does not have an individual approval but may be used under an appropriate group standard

USES

用途与制造

来源：PubChem
Uses

Used as a reagent; [Merck Index]

ALIASES

名称与别名

共 42 条
Diisopropyl azodicarboxylate2446-83-5Diisopropyl azodiformate939987-56-1Diisopropyl azodicarboxylate [MI]Formic acid, azodi-, diisopropyl ester7W701BXX4KEINECS 219-502-81,2-Diazenedicarboxylic acid 1,2-bis(1-methylethyl) esterDTXSID50894754Diazenedicarboxylic acid, bis(1-methylethyl) esterRefChem:587897DTXCID4013243121,2Diazenedicarboxylic acid 1,2bis(1methylethyl) ester219-502-8DiisopropylazodicarboxylateDIADDiisopropyl diazene-1,2-dicarboxylateMFCD00008875propan-2-yl (NE)-N-propan-2-yloxycarbonyliminocarbamate

REACTIONS

参与反应

1,846 条
全部作为反应物作为生成物作为试剂作为催化剂作为溶剂