uspto-grants-2006_08 · 10.6084/m9.figshare.5104873.v1 · US07084147B2
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IDENTITY
结构与身份
- 标准SMILES
- CC(C)OC(=O)/N=N/C(=O)OC(C)C
- InChIKey
- VVWRJUBEIPHGQF-MDZDMXLPSA-N
- 分子式
- C8H14N2O4
- 平均分子量
- 202.21 g/mol
- 单同位素质量
- 202.09535693
COMPUTED
结构计算性质
- XLogP
- 2.6
- 极性表面积
- 77.3 Ų
- 氢键供体
- 0
- 氢键受体
- 4
- 可旋转键
- 4
- 重原子
- 14
- 形式电荷
- 0
- 复杂度
- 211
PROPERTIES
实验与物化性质
Physical Description
Orange liquid; [Merck Index] Pungent odor; [Alfa Aesar MSDS]
GHS
GHS分类
GHS Classification
This chemical does not meet GHS hazard criteria for 35.9% (52 of 145) of reports.
Warning
H315 (62.8%): Causes skin irritation [Warning Skin corrosion/irritation]；H319 (62.8%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]；H335 (61.4%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]；H373 (54.5%): May causes damage to organs through prolonged or repeated exposure [Warning Specific target organ toxicity, repeated exposure]；H411 (61.4%): Toxic to aquatic life with long lasting effects [Hazardous to the aquatic environment, long-term hazard]
P260, P261, P264, P264+P265, P271, P273, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P391, P403+P233, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 145 reports by companies from 21 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Reported as not meeting GHS hazard criteria per 52 of 145 reports by companies.；There are 20 notifications provided by 93 of 145 reports by companies with hazard statement code(s).；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.
HAZARDS
危害信息
Regulatory Information
Status: Active Update: 02-11-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/23916
Diisopropylazodicarboxylate: Does not have an individual approval but may be used under an appropriate group standard
Hazards Summary
A skin, respiratory tract, and strong eye irritant; [Alfa Aesar MSDS] See Diethyl azodicarboxylate.
Hazard Classes and Categories
Skin Irrit. 2 (62.8%)；Eye Irrit. 2 (62.8%)；STOT SE 3 (61.4%)；STOT RE 2 (54.5%)；Aquatic Chronic 2 (61.4%)
REGULATORY
法规信息
Regulatory Information
Status: Active Update: 02-11-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/23916
Diisopropylazodicarboxylate: Does not have an individual approval but may be used under an appropriate group standard
USES
用途与制造
Uses
Used as a reagent; [Merck Index]
ALIASES
名称与别名
Diisopropyl azodicarboxylate2446-83-5Diisopropyl azodiformate939987-56-1Diisopropyl azodicarboxylate [MI]Formic acid, azodi-, diisopropyl ester7W701BXX4KEINECS 219-502-81,2-Diazenedicarboxylic acid 1,2-bis(1-methylethyl) esterDTXSID50894754Diazenedicarboxylic acid, bis(1-methylethyl) esterRefChem:587897DTXCID4013243121,2Diazenedicarboxylic acid 1,2bis(1methylethyl) ester219-502-8DiisopropylazodicarboxylateDIADDiisopropyl diazene-1,2-dicarboxylateMFCD00008875propan-2-yl (NE)-N-propan-2-yloxycarbonyliminocarbamate
REACTIONS
参与反应
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