tert-Butyl-2-ethylperoxyhexanoat

tert-Butyl peroxy-2-ethylhexanoate

HCID 102924CAS 3006-82-4
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Grundinformationen

Standard-SMILES
CCCCC(CC)C(=O)OOC(C)(C)C
InChIKey
WYKYCHHWIJXDAO-UHFFFAOYSA-N
Summenformel
C12H24O3
Durchschnittliche Molmasse
216,32 g/mol
Monoisotopische Masse
216,17254463

Überblick

This peroxide is particularly sensitive to temperature rises and contamination. Above a given "Control Temperature" they decompose violently. It is generally stored or transported with inert solids to mitigate the explosion hazard.

Namen und Bezeichner

Bevorzugter Name
tert-Butyl peroxy-2-ethylhexanoate
IUPAC
tert-butyl 2-ethylhexaneperoxoate
Lokaler Name
tert-Butyl-2-ethylperoxyhexanoat
Englischer Name
tert-Butyl peroxy-2-ethylhexanoate
Summenformel
C12H24O3
Molmasse
216.32

Namen und Synonyme

tert-butyl 2-ethylhexaneperoxoateHexaneperoxoic acid, 2-ethyl-, 1,1-dimethylethyl estertert-Butyl peroxy-2-ethylhexanoatetert-Butyl 2-ethylperoxyhexanoateTrigonox 21INTEROX TBPEHPERCURE OKGA9W7ZS5ICHALOXYD P 1310tert-butyl 2-ethylperhexanoate2-ETHYLHEXANOYL TERT-BUTYL PEROXIDEUNII-KGA9W7ZS5I
Weitere Namen anzeigen
tert-Butyl peroctoateTBPEHInitiating agent OTt-butylperoxyoctoatetert-Butyl peroxy-2-tert-Butyl peroxyoctoateLipid peroxide tert-butylbutyl peroxy-2-ethylhexanoate
Peroxyhexanoic acid, 2-ethyl-, tert-butyl esterDTXSID0027511EINECS 221-110-7EC 221-110-7TERT-BUTYL PEROXY-2-ETHYLHEXANOATE, (TECHNICALLY PURE)TERT-BUTYL PEROXY-2-ETHYLHEXANOATE, [TECHNICALLY PURE]Esperox 28LUPERSOL PDO

Datenbank-Bezeichner

CAS
3006-82-4
PubChem CID
102924
DTXSID
DTXSID0027511
UNII
KGA9W7ZS5I
EC Number
221-110-7
Nikkaji
J3.044I

Eigenschaften

Berechnete Struktureigenschaften

XLogP
4
Polarare Oberfläche (TPSA)
35,5 Ų
H-Brücken-Donoren
0
H-Brücken-Akzeptoren
3
Frei drehbare Bindungen
8
Schwere Atome
15

Experimentelle und physikochemische Eigenschaften

Physical Description · 2 Einträge

This peroxide is particularly sensitive to temperature rises and contamination. Above a given "Control Temperature" they decompose violently. It is generally stored or transported with inert solids to mitigate the explosion hazard.

Liquid; CBI

Physikochemische Eigenschaften

Schmelzpunkt
-30 °C · -30°C
Siedepunkt
248.9 · 248.9±23.0 °C(Predicted)
Dichte
0.89 · 0.89
Dampfdruck
2 Pa · 2Pa at 20℃
Flammpunkt
85 °C · 85°C
pka
-4.8 · -4.8[at 20 ℃]

Sicherheit und Regulatorisches

GHS-Klassifizierung

GHS Classification · 6 Einträge

Danger

H317: May cause an allergic skin reaction [Warning Sensitization, Skin]

P203, P261, P272, P280, P302+P352, P318, P321, P333+P317, P362+P364, P405, and P501 (click each P-code to see the statement)

This chemical does not meet GHS hazard criteria for 1.9% (19 of 1021) of reports.

Danger

H242 (95.9%): Heating may cause a fire [Danger Self-reactive substances and mixtures; Organic peroxides]

Gefahrenhinweise

Regulatory Information · 5 Einträge

Chemical: Hexaneperoxoic acid, 2-ethyl-, 1,1-dimethylethyl ester

Hazard Traits - Reproductive Toxicity

Hexaneperoxoic acid, 2-ethyl-, 1,1-dimethylethyl ester is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Hexaneperoxoic acid, 2-ethyl-, 1,1-dimethylethyl ester are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

REACH registered substance: tert-butyl 2-ethylperoxyhexanoate (EC: 221-110-7)

Hexaneperoxoic acid, 2-ethyl-, 1,1-dimethylethyl ester: Does not have an individual approval but may be used under an appropriate group standard

DOT LabelOrganic Peroxide
Fire HazardsExcerpt from ERG Guide 148 [Organic Peroxides (Heat and Contamination Sensitive / Temperature Controlled)]:
Health HazardsExcerpt from ERG Guide 148 [Organic Peroxides (Heat and Contamination Sensitive / Temperature Controlled)]:
Reactive GroupPeroxides, Organic
Reactivity AlertsExplosive

Sicherheit und Schutzausrüstung

Fire FightingExcerpt from ERG Guide 148 [Organic Peroxides (Heat and Contamination Sensitive / Temperature Controlled)]:
First AidExcerpt from ERG Guide 148 [Organic Peroxides (Heat and Contamination Sensitive / Temperature Controlled)]:
Nonfire Spill ResponseExcerpt from ERG Guide 148 [Organic Peroxides (Heat and Contamination Sensitive / Temperature Controlled)]:
Isolation and EvacuationExcerpt from ERG Guide 148 [Organic Peroxides (Heat and Contamination Sensitive / Temperature Controlled)]:
Personal Protective Equipment (PPE)Excerpt from ERG Guide 148 [Organic Peroxides (Heat and Contamination Sensitive / Temperature Controlled)]:

Sicherheitsdaten

tsca
TSCA listed
ridadr
UN 2143

Chemie und Industrie

Verwendung und Herstellung

U.S. Production2023: 5,500,000 - <7,000,000 lb
Consumer UsesNot Known or Reasonably Ascertainable
Industry UsesCBI
General Manufacturing Information · 2 Einträge

All Other Basic Organic Chemical Manufacturing

Hexaneperoxoic acid, 2-ethyl-, 1,1-dimethylethyl ester: ACTIVE

Anwendungen · 1 Eintrag

VerwendenTert-Butyl peroxy-2-ethylhexanoate (TBPO), also known as Trigonox 21S or PEROXAN PO-30 , is an initiator for (co)polymerization of ethylene, styrene, acrylonitrile and (meth)acrylates. Curing agent for unsaturated polyester resins. It is used for high pressure polymerization of ethylene in both autoclave and tubular processes, usually in combination with other peroxides of varying degrees of activity.

Vor- und nachgelagerte Produkte

Anbieter50 Anbieter

Hebei Chuanghai Biotechnology Co., Ltd+86-17732866630 · [email protected]
武汉欣扬瑞和化学科技有限公司153-07155313 15307155313 · [email protected]
杭州品高化工有限公司0571-87658025 · [email protected]
杭州摩库生物医药科技有限公司+86-057181025280; +8617767106207 · [email protected]
江苏星科元信息科技有限公司400-605-7200 15335295587

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