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Isobutylvinylether
VINYL ISOBUTYL ETHER · IVE · vinoflexmo400* · isobutoxyethene · Lutanol LR 8500 · Vinoflex MO 400 · isobutoxy-ethene · 1-Isobutoxyethene
Identifikatoren & physikalische Daten
| CAS No. | 109-53-5 |
|---|---|
| Summenformel | C6H12O |
| Durchschnittliche Molmasse | 100,16 g/mol |
| Monoisotopische Masse | 100,088815 g/mol |
| SMILES | C=COCC(C)C |
| InChIKey | OZCMOJQQLBXBKI-UHFFFAOYSA-N |
| PubChem CID | 7992 |
| ChEMBL | CHEMBL3183612 |
| EC No. | 203-678-8 |
| DTXSID | DTXSID8029608 |
| Lokaler Name | Isobutylvinylether |
Chemische & physikalische Eigenschaften
| XLogP | 2,2 |
|---|---|
| Polarare Oberfläche (TPSA) | 9,2 |
| H-Brücken-Donoren | 0 |
| H-Brücken-Akzeptoren | 1 |
| Frei drehbare Bindungen | 3 |
| Schwere Atome | 7 |
| Formalladung | 0 |
| Komplexität | 48,1 |
| Stoffklassen | Other Classes -> Ethers, OtherFlammable agents - 3rd degree |
| SpringerMaterials Properties | Boiling point |
| Flammpunkt | 15 °F (NFPA, 2010)8 °F |
| Dampfdruck | 59.5 [mmHg]68 mm Hg ( 20 °C) |
| Physical Description | Vinyl isobutyl ether appears as a clear colorless liquid. May polymerize if contaminated or subjected to heat. If polymerization take place inside a container, the container may violently rupture. Vapors are heavier than air.Clear colorless liquid[CAMEO] |
| Schmelzpunkt | -112 °C |
| Siedepunkt | 83 °C |
| Dichte | 0.769 |
| Dampfdichte | 3.45 (vs air) |
| Brechungsindex | n20/D 1.395(lit.) |
| Lagerbedingungen | Flammables area |
| Aggregatzustand | clear liquid |
| Farbe | Colorless to Almost colorless |
| Löslichkeit | 0.7 g/L (25 ºC) |
| BRN | 1560159 |
| Henry-Konstante | 3.9×10-3 mol/(m3Pa) at 25℃, Raventos-Duran et al. (2010) |
| Dielektrizitätskonstante | 3.3399999999999999 |
| InChI | 1S/C6H12O/c1-4-7-5-6(2)3/h4,6H,1,5H2,2-3H3 |
| InChIKey | OZCMOJQQLBXBKI-UHFFFAOYSA-N |
| SMILES | CC(C)COC=C |
| LogP (Verteilungskoeffizient) | 3.07 at 25℃ |
| CAS Datenbank | 109-53-5(CAS DataBase Reference) |
| NIST chemische Informationen | Vinylisobutyl ether(109-53-5) |
| EPA chemische Informationen | Propane, 1-(ethenyloxy)-2-methyl- (109-53-5) |
Sicherheit & Vorschriften
| GHS-Einstufung | This chemical does not meet GHS hazard criteria for 3.8% (8 of 213) of reports.DangerH225 (96.2%): Highly Flammable liquid and vapor [Danger Flammable liquids]P210, P233, P240, P241, P242, P243, P264, P264+P265, P273, P280, P302+P352, P303+P361+P353, P305+P351+P338, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403+P235, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 213 reports by companies from 10 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies. |
|---|---|
| Regulatorische Informationen | Chemical: Propane, 1-(ethenyloxy)-2-methyl-Propane, 1-(ethenyloxy)-2-methyl- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Propane, 1-(ethenyloxy)-2-methyl- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)Status: Active Update: 31-03-2023 https://echa.europa.eu/registration-dossier/-/registered-dossier/2053Propane, 1-(ethenyloxy)-2-methyl-: Does not have an individual approval but may be used under an appropriate group standardThe New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.) |
| DOT-Kennzeichnung | Flammable Liquid |
| Brandgefahren | Excerpt from ERG Guide 127 [Flammable Liquids (Water-Miscible)polymerization hazard]:· HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. |
| Gesundheitsgefahren | Excerpt from ERG Guide 127 [Flammable Liquids (Water-Miscible)polymerization hazard]:· Inhalation or contact with material may irritate or burn skin and eyes. |
| Gefahrenübersicht | May polymerizeForms explosive peroxides on exposure to air[CAMEO] A skin, eye, nose, and throat irritant[NJ-HSFS] May form explosive peroxidesAn irritant[Sigma-Aldrich MSDS] Vinyl isobutyl ether, stabilized (UN1304) has warning of explosive polymerization[ERG 2016] |
| DOT-Nummer und Handbuch | 1304 127P |
| Reaktive Gruppe | Ethers |
| Reactivity Alerts | Highly Flammable |
| Reactivity Profile | VINYL ISOBUTYL ETHER is a colorless, moderately toxic liquid, highly flammable. A very dangerous fire hazard when exposed to heat, flame or strong oxidizing agents. Highly explosive in the form of vapor when exposed to open flame or sparks. |
| DOT Hazard Classification | Vinyl isobutyl ether, stabilizedUN1304Class 3 Flammable and combustible liquid (49 eCFR § 173.120)PG II: the degree of danger presented by the material is medium |
| Air and Water Reactions | Highly flammable. Less dense than water and very slightly soluble in water. Tends to form explosive peroxides when exposed to air. When ethers containing peroxides are heated (distilled) they can detonate [Lewis, 3rd ed., 1993, p. 728]. |
| Peroxide Forming Chemical | Isobutyl vinyl etherB: Compounds that form peroxides on concentration (distillation/evaporation)Kelly |
| Brandbekämpfung | Excerpt from ERG Guide 127 [Flammable Liquids (Water-Miscible)polymerization hazard]: |
| Freisetungsmaßnahmen | · CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area. |
| Erste Hilfe | Excerpt from ERG Guide 127 [Flammable Liquids (Water-Miscible)polymerization hazard]:General First Aid: |
| Expositionsschutz und Persönliche Schutzausrüstung | · Wear positive pressure self-contained breathing apparatus (SCBA).20.0 [ppm] |
| Freisetung ohne Brand | Excerpt from ERG Guide 127 [Flammable Liquids (Water-Miscible)polymerization hazard]: |
| Isolation and Evacuation | Excerpt from ERG Guide 127 [Flammable Liquids (Water-Miscible)polymerization hazard]:Immediate precautionary measure |
| Personal Protective Equipment (PPE) | Excerpt from ERG Guide 127 [Flammable Liquids (Water-Miscible)polymerization hazard]: |
| Emergency Response Planning Guidelines | CAUTION: The majority of these products have a very low flash point. Use of water spray when fighting fire may be inefficient. |
| Toxicity Data | LCLo (rat) = 16,000 ppm/4hr |
| F | 9 |
| Wassergefährdungsklasse (WGK) | 1 |
| TSCA-Inventar-Status | TSCA listed |
| UN-Transportnummer | UN 1304 (VINYL ISOBUTYL ETHER, STABILIZED) |
| Zollcode | 29091990 |
| RTECS-Nr. | KO1300000 |
| R-Sätze (R) | 11-38-52/53 |
| Toxizität | rabbit,LD50,skin,20mL/kg (20mL/kg),American Industrial Hygiene Association Journal. Vol. 23, Pg. 95, 1962. |
| Gefahrensymbole | F,Xi |
| Sicherheitshinweise (S) | 16-23-24/25-33-37-61 |
| Gefahrenklasse | 3Aquatic Chronic 3Flam. Liq. 2Skin Irrit. 2 |
| Verpackungsgruppe | II |
| Lagerklasse | 3 - Flammable liquids |
Anwendungen & Verwendung
Verwenden
Isobutyl vinyl ether is use in preparation method and formula of bulk polymerized Chloroether resin.