Potassium Hydroxide → HCID 13043902, Verbindung

HRID 1065777

Reaktionsgleichung

Reaktionsgleichung von HRID 1065777
[NH2:1][C:2]1[C:7]([Cl:8])=[C:6]([CH3:9])[C:5]([Cl:10])=[C:4]([CH3:11])[N:3]=1.[OH-].[K+].[N+:14]([C:17]1[CH:22]=[C:21]([N+:23]([O-:25])=[O:24])[CH:20]=[C:19]([C:26]([F:29])([F:28])[F:27])[C:18]=1Cl)([O-:16])=[O:15]>CN(C)C=O>[Cl:8][C:7]1[C:2]([NH:1][C:18]2[C:19]([C:26]([F:28])([F:29])[F:27])=[CH:20][C:21]([N+:23]([O-:25])=[O:24])=[CH:22][C:17]=2[N+:14]([O-:16])=[O:15])=[N:3][C:4]([CH3:11])=[C:5]([Cl:10])[C:6]=1[CH3:9]

Komponenten

5

Edukt 3

HCID 14797Potassium HydroxideHCID 67851Benzene, 2-chloro-1,5-dinitro-3-(trifluoromethyl)-HCID 122510103,5-Dichloro-4,6-dimethylpyridin-2-amine

Produkt 1

HCID 13043902HCID 13043902, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 6228DimethylformamideLösungsmittel2×

Versuchsvorschrift

In 20 ml. of dimethylformamide, 1.9 g. of 2-amino-3,5-dichloro-4,6-dimethylpyridine was dissolved and 0.7 g. of powdery potassium hydroxide was gradually added with stirring and a solution of 2.7 g. of 2,4-dinitro-6-trifluoromethylchlorobenzene in 10 ml. of dimethylformamide was added dropwise at room temperature to react them for about 10 hours. The reaction mixture was treated as the process of Preparation No. 7 to obtain 1.6 g. of the object compound having the melting point of 131° to 133° C.

Aufarbeitung

  1. customto react them for about 10 hours
  2. additionThe reaction mixture was treated as the process of Preparation No
  3. custom7 to obtain 1.6 g

Quellen und Nachweise

ORD-Eintrag
ord-1c7e097d51ff48ea8a22f98e6342a625
Quelldatensatz
uspto-grants-1982_05
Patentnummer
US04331670

Verknüpfte Notizen

Wird geladen…