HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Phenol → Diphenyl carbonate
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | Phenol | HCID 996 | — |
| Edukt | Phenyl chloroformate | HCID 15891 | — |
| Katalysator | Titanium mononitride | HCID 93091 | — |
| Produkt | Diphenyl carbonate | HCID 7597 | — |
Reaktionsschritte
Example 1 was repeated with 14.1 g of a powdered titanium nitride from H. C. Starck at 140° C. After 2 hours' reaction time, phenol conversion was 21.6%, wherein 0.03 g of phenyl chloroformate and 34.3 g of diphenyl carbonate were formed. Selectivity for carbonates was approximately 99%.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US05679825 |
| Quelldatensatz | uspto-grants-1997_10 |
| ORD ID | ord-30e6626a19f74b55b2109bb371db2ccb |
| Quellennotiz | uspto-grants-1997_10 |