HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
5H-Dibenzo[a,d]cyclohepten-5-one → dibenzo[a,d]cyclooctene-6,12(5H,7H)-dione
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | 5H-Dibenzo[a,d]cyclohepten-5-one | HCID 16679 | — |
| Edukt | 2-Bromo-6,12-dioxo-5,6,7,12-tetrahydrodibenzo[a,d]cyclooctene | HCID 15580927 | — |
| Edukt | 2-Chloro-6,12-dioxo-5,6,7,12-tetrahydrodibenzo[a,d]cyclooctene | HCID 15580928 | — |
| Edukt | 2-Fluoro-6,12-dioxo-5,6,7,12-tetrahydrodibenzo[a,d]cyclooctene | HCID 20480890 | — |
| Lösungsmittel | 1-Bromo-2-chlorobenzene | HCID 12754 | — |
| Lösungsmittel | 3-bromo-5H-dibenzo[a,d]cyclohepten-5-one | HCID 11483010 | — |
| Lösungsmittel | 3-Chloro-5H-dibenzo[A,D][7]annulen-5-one | HCID 12690610 | — |
| Lösungsmittel | 3-fluoro-5H-dibenzo[a,d]cyclohepten-5-one | HCID 15628590 | — |
| Produkt | dibenzo[a,d]cyclooctene-6,12(5H,7H)-dione | HCID 12552292 | — |
Reaktionsschritte
Employing the procedure substantially as described in Example 1, Steps A through D, but substituting for the 5H-dibenzo[a,d]cyclohepten-5-one used in Step A thereof an equimolecular amount of 3-bromo-5H-dibenzo[a,d]cyclohepten-5-one, 3-chloro-5H-dibenzo[a,d]cyclohepten-5-one, or 3-fluoro-5H-dibenzo[a,d]cyclohepten-5-one, and o-chlorobromobenzene as solvent in Step B, there are produced, respectively, 2-bromo-6,12-dioxo-5,6,7,12-tetrahydrodibenzo[a,d]cyclooctene, m.p. 133°-138° C., 2-chloro-6,12-dioxo-5,6,7,12-tetrahydrodibenzo[a,d]cyclooctene, m.p. 148°-149° C., and 2-fluoro-6,12-dioxo-5,6,7,12-tetrahydrodibenzo[a,d]cyclooctene.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US04414154 |
| Quelldatensatz | uspto-grants-1983_11 |
| ORD ID | ord-b06949016c6a4ab89e8f6bb23e25f2c2 |
| Quellennotiz | uspto-grants-1983_11 |