tert-Butyl hydroperoxide → Tris-(4-benzoyloxy-2,2,6,6-tetramethyl-piperidin-1-yloxy)octadecane

Beteiligte Stoffe

Reaktionsschritte

A mixture of 80 mmol of 4-benzoyloxy-1-oxyl-2,2,6,6-tetramethylpiperidine, 250 mmol of 90% tert-butyl hydroperoxide, 125 grams of octadecane and 5 mmol of molybdenum trioxide is heated ait 140° C. in a Fischer-Porter prerssure bottle till the red color of the N-oxyl compound is no longer visible. The reaction mixture is purified by flash chromatography.

Herkunft & Nachweise