Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|
| Edukt | Hypochlorite | HCID 61739 | — |
| Edukt | Gluconate | HCID 6419706 | — |
| Produkt | D-Arabinose | HCID 66308 | — |
Reaktionsschritte
The hypochlorite solution is metered into the warm gluconate solution at a rate such that the addition is complete within a period of about 10-60 minutes, preferably about 30 minutes. The hypochlorite solution can, of course, also be metered in over a longer period, and this may be unavoidable in the case of very large batches. However, as a rule, the addition is effected in as short a time as possible. Thereafter, the mixture is stirred for a further brief period until the excess hypochlorite has disappeared. D-arabinose may then be isolated in a conventional manner. The yield of D-arabinose is about 70-75%, relative to the starting D-glucose, and this is achieved even when the crude fermentation solution from oxidation of D-glucose is employed.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| Patentnummer | US04355158 |
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| Quelldatensatz | uspto-grants-1982_10 |
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| ORD ID | ord-87c11765ac8f46998e37ddcc3cf2b0b1 |
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| Quellennotiz | uspto-grants-1982_10 |
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