4,4-di(1'-methylpropyl)-4,5-dihydro-3H-dinaphtho[2,1-c:1',2'-e]phosphepinium bromide → 2-Di(1'-methylpropyl)phosphinomethyl-2'-methyl-1,1'-binaphthyl

Beteiligte Stoffe

Rolle	Name	HCID	Einwaage
Edukt	4,4-di(1'-methylpropyl)-4,5-dihydro-3H-dinaphtho[2,1-c:1',2'-e]phosphepinium bromide	HCID 18929278	—
Edukt	Aluminium lithium hydride	HCID 21226445	—
Lösungsmittel	O-Xylene	HCID 7237	—
Produkt	2-Di(1'-methylpropyl)phosphinomethyl-2'-methyl-1,1'-binaphthyl	HCID 19690364	—

Reaktionsschritte

4 g (7.9 mmol) of 4,4-di(1'-methylpropyl)-4,5-dihydro-3H-dinaphtho[2,1-c:1',2'-e]phosphepinium bromide are suspended in 70 ml of absolute xylene and reacted with 400 mg (10.5 mmol) of lithium aluminum hydride using a method analogous to Example 5.

Herkunft & Nachweise

DOI	10.6084/m9.figshare.5104873.v1
Patentnummer	US05728886
Quelldatensatz	uspto-grants-1998_03
ORD ID	ord-9144b195488a484e95660584bc9d7fc6
Quellennotiz	uspto-grants-1998_03