HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Methanol → Dimethyl 2-formylcyclopropane-1,1-dicarboxylate
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | Methanol | HCID 887 | — |
| Edukt | Acrolein | HCID 7847 | — |
| Edukt | Dimethyl bromomalonate | HCID 70087 | — |
| Edukt | 1,1-Diethyl 2-formylcyclopropane-1,1-dicarboxylate | HCID 533739 | — |
| Lösungsmittel | Ethanol | HCID 702 | — |
| Produkt | Dimethyl 2-formylcyclopropane-1,1-dicarboxylate | HCID 10899359 | — |
Reaktionsschritte
By following the procedure of D. T. Warner, cited above, used for preparing diethyl 2-formylcyclopropane-1,1-dicarboxylate from acrolein but using equivalent amount of dimethylbromomalonate and methanol instead of diethylbromomalonate and ethanol, respectively, the title compound, nmr (CDCl3) δ1.98 (m,2H), 2.80(m, 1H), 3.79(s,6H), 8.82(d, J = 4 cps, 1H), is obtained.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US04036856 |
| Quelldatensatz | uspto-grants-1977_07 |
| ORD ID | ord-c1c5b39a73fb4e5b8bb20cf0d7522091 |
| Quellennotiz | uspto-grants-1977_07 |