HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Methyl Ethyl Ketone → 1,4,5-Triphenyl-3-(7-bromoheptyl)imidazol-2-one
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | Methyl Ethyl Ketone | HCID 6569 | — |
| Edukt | Potassium Carbonate | HCID 11430 | — |
| Edukt | 1,4,5-Triphenyl-1,3-dihydro-2H-imidazol-2-one | HCID 628544 | — |
| Edukt | 4,4-Dibromoheptane | HCID 21679102 | — |
| Produkt | 1,4,5-Triphenyl-3-(7-bromoheptyl)imidazol-2-one | HCID 22916388 | 46% |
Reaktionsschritte
A mixture of 1,4,5-triphenylimidazol-2-one (15.3 g), dibromoheptane (50.6 g) and potassium carbonate (13.8 g) was heated at reflux temperature in dry butanone (750 ml) for 20 hours. The mixture was cooled, filtered and the filtrate evaporated to an oil which was chromatographed on silica gel (hexane/ethyl acetate) to give 1,4,5-triphenyl-3-(7-bromoheptyl)imidazole-2-one (11.1 g, 46%) as an oil.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US05648373 |
| Quelldatensatz | uspto-grants-1997_07 |
| ORD ID | ord-37c6d3059e04483fafa6f3e031bbe891 |
| Quellennotiz | uspto-grants-1997_07 |