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HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
HRID 341894Erstellt: 23. Oktober 2026

4-Chloro-o-xylene → 2,2'-Dichloro-4,4',5,5'-tetramethylbenzophenone

https://huagongshe.com/de/reaction/341894

Reaktionsgleichung

Beteiligte Stoffe

RolleNameHCIDEinwaage
Edukt4-Chloro-o-xyleneHCID 32886—
EduktOxalyl chlorideHCID 65578—
Edukt4,4'-Carbonyldiphthalic anhydrideHCID 75498—
Produkt2,2'-Dichloro-4,4',5,5'-tetramethylbenzophenoneHCID 15027172—

Reaktionsschritte

Specific benzophenonetetracarboxylic dianhydrides preferred in this invention are readily available from commercial sources or synthesis. For instance, 3,3',4,4'-benzophenonetetracarboxylic dianhydride (D1) is available from Aldrich Chemical Co., Inc. (1001 W. St. Paul Ave., Milwaukee, Wis. 53233). 2,2'-Dichloro-4,4',5,5'-benzophenone tetracarboxylic dianhydride (D2) is available from 4-chloro-o-xylene by Friedel-Crafts acylation with oxalyl chloride to give 2,2'dichloro-4,4',5,5',-tetramehtylbenzophenone, followed by oxidation with nitric acid and dehydration of the resulting tetracarboxylic acid as described by Falcigno, et al., J. Poly. Sci. 1992, 30, 1433.

Herkunft & Nachweise

DOI10.6084/m9.figshare.5104873.v1
PatentnummerUS05856431
Quelldatensatzuspto-grants-1999_01
ORD IDord-6fbd979732f74fb1941246ded6b35f34
Quellennotizuspto-grants-1999_01