HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
4-Chloro-o-xylene → 2,2'-Dichloro-4,4',5,5'-tetramethylbenzophenone
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | 4-Chloro-o-xylene | HCID 32886 | — |
| Edukt | Oxalyl chloride | HCID 65578 | — |
| Edukt | 4,4'-Carbonyldiphthalic anhydride | HCID 75498 | — |
| Produkt | 2,2'-Dichloro-4,4',5,5'-tetramethylbenzophenone | HCID 15027172 | — |
Reaktionsschritte
Specific benzophenonetetracarboxylic dianhydrides preferred in this invention are readily available from commercial sources or synthesis. For instance, 3,3',4,4'-benzophenonetetracarboxylic dianhydride (D1) is available from Aldrich Chemical Co., Inc. (1001 W. St. Paul Ave., Milwaukee, Wis. 53233). 2,2'-Dichloro-4,4',5,5'-benzophenone tetracarboxylic dianhydride (D2) is available from 4-chloro-o-xylene by Friedel-Crafts acylation with oxalyl chloride to give 2,2'dichloro-4,4',5,5',-tetramehtylbenzophenone, followed by oxidation with nitric acid and dehydration of the resulting tetracarboxylic acid as described by Falcigno, et al., J. Poly. Sci. 1992, 30, 1433.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US05856431 |
| Quelldatensatz | uspto-grants-1999_01 |
| ORD ID | ord-6fbd979732f74fb1941246ded6b35f34 |
| Quellennotiz | uspto-grants-1999_01 |