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HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
HRID 345874Erstellt: 24. Oktober 2026

5,5,8,8-Tetramethyl-5,6,7,8-tetrahydronaphthalene-2-carbonyl chloride → Methyl 4-methyl-3-[[(5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-naphthalenyl)carbonyl]thio]benzoate

https://huagongshe.com/de/reaction/345874

Reaktionsgleichung

Beteiligte Stoffe

RolleNameHCIDEinwaage
Edukt5,5,8,8-Tetramethyl-5,6,7,8-tetrahydronaphthalene-2-carbonyl chlorideHCID 2795466—
EduktHCID 13633551HCID 13633551—
LösungsmittelTriethylamineHCID 8471—
ProduktMethyl 4-methyl-3-[[(5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-naphthalenyl)carbonyl]thio]benzoateHCID 1363356388,3%

Reaktionsschritte

In a manner analogous to Example 1(a), starting with 1.83 g (10 mmol) of methyl 3-mercapto-4-methyl benzoate, 1.5 ml of triethylamine and 2.76 g (11 mmol) of 5, 6, 7, 8-tetrahydro-5, 5, 8, 8-tetramethyl-2-naphtoyl chloride, methyl 4-methyl-3-(5, 6, 7, 8-tetrahydro-5, 5, 8, 8-tetramethyl-2-naphtoylthio)benzoate (3.50 g; 88%) is produced.

Herkunft & Nachweise

DOI10.6084/m9.figshare.5104873.v1
PatentnummerUS05059621
Quelldatensatzuspto-grants-1991_10
ORD IDord-1333626e475440aa9ceac848d318fef1
Quellennotizuspto-grants-1991_10