Phenol → 2-Decylthio-3-hydroxynorbornane

Beteiligte Stoffe

Reaktionsschritte

A reaction was conducted as described in Example 1 except that tris[tris(dimethylamino)phosphoranylidene-amino]phosphine oxide was replaced with the same molar amount of a partially hydrated tris[tris(dimethylamino)phosphoranylidene-amino]phosphine oxide, [(Me2N)3P=N]3P=O.0.29H2O, phenol was replaced with the same molar amount of decanethiol and PGE was replaced with 2,3-epoxynorbornane. Desired 2-decylthio-3-hydroxynorbornane was formed in an analytical yield of 95% and isolated in a yield of 90%.

Herkunft & Nachweise