HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Acetic Anhydride → Ethyl 2-(2,4-dichloro-3,6-difluorobenzoyl)-3-ethoxyacrylate
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | Acetic Anhydride | HCID 7918 | — |
| Edukt | Ethyl orthoformate | HCID 31214 | — |
| Edukt | Ethyl (2,4-dichloro-3,6-difluorobenzoyl)acetate | HCID 15070035 | — |
| Produkt | Ethyl 2-(2,4-dichloro-3,6-difluorobenzoyl)-3-ethoxyacrylate | HCID 53750212 | — |
Reaktionsschritte
13.7 g of ethyl (2,4-dichloro-3,6-difluorobenzoyl)acetate are heated under reflux with 10.25 g of triethyl orthoformate and 11.8 g of acetic anhydride for 2 hours. The mixture is then concentrated in vacuo up to a bath temperature of 140° C. and 15.7 g of ethyl 2-(2,4-dichloro-3,6-difluorobenzoyl)-3-ethoxy-acrylate are obtained as an oil, nD25 : 1.5302.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US05416096 |
| Quelldatensatz | uspto-grants-1995_05 |
| ORD ID | ord-12d109b8572e454597f795a576fdd579 |
| Quellennotiz | uspto-grants-1995_05 |