HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Triethylamine → HCID 53788593, Verbindung
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | Triethylamine | HCID 8471 | — |
| Edukt | Cyclopentene | HCID 8882 | — |
| Edukt | 3-Iodobenzyl alcohol | HCID 42300 | — |
| Edukt | Tri-o-tolylphosphine | HCID 80271 | — |
| Katalysator | palladium(II) acetate | HCID 167845 | — |
| Lösungsmittel | Methanol | HCID 887 | — |
| Produkt | HCID 53788593 | HCID 53788593 | 232,3% |
Reaktionsschritte
According to example 61, 10.0 g of 3-iodobenzyl alcohol (Aldrich) was treated with 30 mL of cyclopentene using 0.96 g of Pd(OAc)2, 2.60 g of tri-ortho-tolylphosphine, and 6.6 mL of Et3N. The resulting olefin mixture was hydrogenated for 2.5 h using 0.62 g of 5% Pt(C) in MeOH to afford 5.77 g (76%) of 3-cyclopentylbenzyl alcohol as a light yellow liquid.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US06140100 |
| Quelldatensatz | uspto-grants-2000_10 |
| ORD ID | ord-16b62740afed44928af8603f652819cf |
| Quellennotiz | uspto-grants-2000_10 |