HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Ethanol → 5-Bromo-2-[3,4-dihydro-1(2H)-quinolinyl]aniline
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | Ethanol | HCID 702 | — |
| Edukt | 1-(4-Bromo-2-nitrophenyl)-1,2,3,4-tetrahydroquinoline | HCID 13812927 | — |
| Katalysator | Platinum | HCID 23939 | — |
| Lösungsmittel | Benzene | HCID 241 | — |
| Produkt | 5-Bromo-2-[3,4-dihydro-1(2H)-quinolinyl]aniline | HCID 13812931 | 100% |
Reaktionsschritte
1-(4-Bromo-2-nitrophenyl)-1,2,3,4-tetrahydroquinoline (11.6 g, 0.035 mole) was dissolved in benzene (125 ml), and ethanol added (75 ml), followed by 1% platinum-on-charcoal (0.40 g). The mixture was shaken under an initial pressure of 56 psi for 6.5 hours. The mixture was filtered and the filtrate was evaporated at 50° C. under vacuum to provide 10.6 g (100%) of product, as a gum.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US04723007 |
| Quelldatensatz | uspto-grants-1988_02 |
| ORD ID | ord-be31b5d785ad45829427ebbf59eaec37 |
| Quellennotiz | uspto-grants-1988_02 |