HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Ethyl Acetate → (2E,6E)-2-[(3E)-4,8-Dimethylnona-3,7-dien-1-YL]-6-methylocta-2,6-diene-1,8-diol
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | Ethyl Acetate | HCID 8857 | — |
| Edukt | Aluminiumhydride | HCID 21584524 | — |
| Edukt | HCID 53654873 | HCID 53654873 | — |
| Lösungsmittel | Diethyl Ether | HCID 3283 | — |
| Produkt | (2E,6E)-2-[(3E)-4,8-Dimethylnona-3,7-dien-1-YL]-6-methylocta-2,6-diene-1,8-diol | HCID 6373042 | — |
Reaktionsschritte
The ester thus obtained was further reduced by aluminum hydride (prepared from 760 mg of lithium aluminum hydride and 880 mg of aluminum chloride) in 7 ml of ether. After completion of the reaction, ethyl acetate was added to the reaction mixture, and the precipitate was filtered off. The filtrate was evaporated to dryness, yielding 3.5 g of the desired product.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US04260551 |
| Quelldatensatz | uspto-grants-1981_04 |
| ORD ID | ord-6417daee1ff942c6842215cc7af87313 |
| Quellennotiz | uspto-grants-1981_04 |