HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Phenol → 4,4,4'4'-Tetra(3-isopropyl-4-hydroxyphenyl)bicyclohexene
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | Phenol | HCID 996 | — |
| Edukt | 2-Isopropylphenol | HCID 6943 | — |
| Edukt | (1,1'-Bicyclohexyl)-4-one | HCID 41690 | — |
| Lösungsmittel | Methanol | HCID 887 | — |
| Produkt | 4,4,4'4'-Tetra(3-isopropyl-4-hydroxyphenyl)bicyclohexene | HCID 18446146 | 232,7% |
Reaktionsschritte
The same method as specified in Reference Example 1 was used, except that 236.8 g of 0-isopropyl phenol and 23.7 g of methanol were used instead of 209.4 g of phenol and 18.9 g of methanol, and that a solution made of 39.0 g of 4,4′-bicyclohexanon and 39.0 g of 0-isopropyl phenol dissolved in 15.8 g of methanol was used instead of a solution made of 24.2 g of 4,4′-bicyclohexanon and 24.2 g of phenol dissolved in 24.2 g of methanol, to achieve reaction, neutralization, crystallization and filtering to obtain 175.9 g of 4,4,4′4′-tetra(3-isopropyl-4-hydroxyphenyl)bicyclohexene as white solid (still wet with the solution).
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US07196232B2 |
| Quelldatensatz | uspto-grants-2007_03 |
| ORD ID | ord-615c9b1d0f7a4ec4b34e754003081310 |
| Quellennotiz | uspto-grants-2007_03 |