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HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
HRID 462487Erstellt: 24. Oktober 2026

Formaldehyde → 4,4-Di(hydroxymethyl)bicyclo(2.2.1)heptene

https://huagongshe.com/de/reaction/462487

Reaktionsgleichung

Beteiligte Stoffe

RolleNameHCIDEinwaage
EduktFormaldehydeHCID 712—
EduktBicyclo(2.2.1)hept-5-ene-2-carboxaldehydeHCID 95117—
Produkt4,4-Di(hydroxymethyl)bicyclo(2.2.1)hepteneHCID 110917—

Reaktionsschritte

The synthesis of this chemical compound is depicted in Table I. The synthesis consists of the reaction of cyclopentene with acrolein to produce 5-norbornene-2-al. Reaction of 5-norbornene-2-al with formaldehyde results in the formation of 5-norbornene-2,2-dimethanol. Mild oxidation of the latter compound with dibutylstannic oxide yields the 3,9-bis(5'-norbornene-2'yl)-1,5,7,11-tetraoxaspiro[5.5]undecane.

Herkunft & Nachweise

DOI10.6084/m9.figshare.5104873.v1
PatentnummerUS04515912
Quelldatensatzuspto-grants-1985_05
ORD IDord-28176567ee1b4f57bad6f55744d701ad
Quellennotizuspto-grants-1985_05