HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
p-Toluidine → N-(p-phenylbenzylidene)-p-methylaniline
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | p-Toluidine | HCID 7813 | — |
| Edukt | (1,1'-Biphenyl)-4-carboxaldehyde | HCID 76689 | — |
| Lösungsmittel | Toluene | HCID 1140 | — |
| Produkt | N-(p-phenylbenzylidene)-p-methylaniline | HCID 13017554 | — |
Reaktionsschritte
p-Toluidine (0.20 mole), 4-biphenylcarboxaldehyde (0.20 mole), and IRC-50 (weakly acidic) ion exchange resin (0.5 g.) were azeotropically refluxed in toluene (150 cc). The required amount of water had been removed after 3 hours. The solvent was removed on the rotary evaporator and the residue was recrystallized with 95% ethanol to yield N-(p-phenylbenzylidene)-p-methylaniline; m.p. 137°-139° C.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US04176198 |
| Quelldatensatz | uspto-grants-1979_11 |
| ORD ID | ord-6885f8cc803248b0b118c62099c312e2 |
| Quellennotiz | uspto-grants-1979_11 |