HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Phenyl Trifluoromethanesulfonate → 2-Triethylsilyl-5-phenyl-4-furaldehyde
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | Phenyl Trifluoromethanesulfonate | HCID 548641 | — |
| Edukt | 3-Furancarboxaldehyde, 5-(triethylsilyl)- | HCID 10878438 | — |
| Edukt | HCID 178506926 | HCID 178506926 | — |
| Katalysator | Zincchloride | HCID 3007855 | — |
| Katalysator | Tetrakis(triphenylphosphine)palladium | HCID 11979704 | — |
| Produkt | 2-Triethylsilyl-5-phenyl-4-furaldehyde | HCID 19433144 | — |
Reaktionsschritte
Treatment of 2-triethylsilyl-4-furaldehyde with lithio N,N,N'-trimethylethylenediamine, followed by phenyl trifluoromethanesulfonate in the presence of anhydrous zinc chloride and tetrakis (triphenylphosphine) palladium (o) and work up gives the titled aldehyde.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US05298633 |
| Quelldatensatz | uspto-grants-1994_03 |
| ORD ID | ord-018130448c9e46a38cdbaf860961e47e |
| Quellennotiz | uspto-grants-1994_03 |