HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Acetic acid, (1,3-dihydro-2H-inden-2-ylidene)-, ethyl ester → Ethyl 2-(2,3-dihydro-1H-inden-2-yl)acetate
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | Acetic acid, (1,3-dihydro-2H-inden-2-ylidene)-, ethyl ester | HCID 10631946 | — |
| Katalysator | Palladium | HCID 23938 | — |
| Lösungsmittel | Ethyl Acetate | HCID 8857 | — |
| Produkt | Ethyl 2-(2,3-dihydro-1H-inden-2-yl)acetate | HCID 10104359 | 94% |
Reaktionsschritte
To a solution of ethyl 1,3-dihydro-2H-inden-2-ylideneacetate (302 mg, 1.49 mmol) in EtOAc (10 mL) was added 5% Pd/C (76 mg) and H2 was bubbled through the slurry for 20 h. The slurry was then filtered through Celite and the organic solution was concentrated in vacuo. Ethyl 2,3-dihydo-1H-inden-2-ylacetate (285 mg, 94%) was isolated as a colorless oil without purification.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US06713471B1 |
| Quelldatensatz | uspto-grants-2004_03 |
| ORD ID | ord-a54f5142b7224ac08d0149ff911a7335 |
| Quellennotiz | uspto-grants-2004_03 |