HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Water → Ethanethioic acid cis-(+/-)-S-[5-[[(aminocarbonyl)oxy]methyl]tetrahydro-3-furanyl]ester
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | Water | HCID 962 | — |
| Edukt | Trichloroacetyl isocyanate | HCID 76400 | — |
| Edukt | Ethanethioic acid cis (+/-)-S-[tetrahydro-5-(hydroxymethyl)-3-furanyl]ester | HCID 86750314 | — |
| Lösungsmittel | Acetic Acid | HCID 176 | — |
| Lösungsmittel | Dichloromethane | HCID 6344 | — |
| Lösungsmittel | Tetrahydrofuran | HCID 8028 | — |
| Lösungsmittel | Tetrabutylammonium Fluoride | HCID 2724141 | — |
| Produkt | Ethanethioic acid cis-(+/-)-S-[5-[[(aminocarbonyl)oxy]methyl]tetrahydro-3-furanyl]ester | HCID 86750313 | — |
Reaktionsschritte
The title compound is prepared by the procedure of Example 7 using 0.28 g of product from Example 9 in 20 ml of methylene chloride, 0.208 ml of trichloroacetyl isocyanate, 0.80 ml of acetic acid, 6.79 ml of 1M tetrabutylammonium fluoride in tetrahydrofuran and 0.37 ml of water to give 0.320 g of the desired product.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US05623081 |
| Quelldatensatz | uspto-grants-1997_04 |
| ORD ID | ord-5ce210a07f8045098a967abf4013a763 |
| Quellennotiz | uspto-grants-1997_04 |