Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|
| Edukt | Sulfuric Acid | HCID 1118 | — |
| Edukt | Sodium Hydroxide | HCID 14798 | — |
| Edukt | Potassium Dichromate | HCID 24502 | — |
| Edukt | 4-(4-Chloro-benzylamino)-cyclohexanol | HCID 13670658 | — |
| Produkt | 4-[N-(4-Chloro-benzyl)-amino]-cyclohexanone | HCID 13670664 | — |
Reaktionsschritte
23.9 g (0.01 Mol) of 4-[N-(4-chlorobenzyl)amino]-cyclohexanol are suspended in 125 ml of ice water and 32 ml of concentrated sulphuric acid are added. Then 29.4 g (0.1 Mol) of potassium dichromate are added in 2 batches and the mixture is heated for 5 hours at 50° C. It is then cooled, made alkaline with sodium hydroxide solution and extracted with chloroform. After concentration, a yellowish oily liquid is obtained.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patentnummer | US04731374 |
|---|
| Quelldatensatz | uspto-grants-1988_03 |
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| ORD ID | ord-d1739173b3a94ec3a9c1ce4f98774183 |
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| Quellennotiz | uspto-grants-1988_03 |
|---|
