HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
[1,3]Oxathiolo[5,4-c]pyridin-6-ylmethanol → [1,3]Oxathiolo[5,4-c]pyridine-6-carbaldehyde
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | [1,3]Oxathiolo[5,4-c]pyridin-6-ylmethanol | HCID 67426109 | — |
| Katalysator | HCID 178418406 | HCID 178418406 | — |
| Lösungsmittel | Dichloromethane | HCID 6344 | — |
| Produkt | [1,3]Oxathiolo[5,4-c]pyridine-6-carbaldehyde | HCID 59254367 | 62,3% |
Reaktionsschritte
[1,3]oxathiolo[5,4-c]pyridine-6-methanol (0.92 g, 5.44 mmole) was treated with manganese (IV) oxide (3.83 g, 44 mmole) at RT in DCM (50 mL) to afford the aldehyde (567 mg, 62%) as a solid; MS (+ve ion electrospray) m/z 168 (MH+).
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US07691850B2 |
| Quelldatensatz | uspto-grants-2010_04 |
| ORD ID | ord-e811c26613054254a23fc21a8c0d7428 |
| Quellennotiz | uspto-grants-2010_04 |