HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Tryptophol → 1-(Acetamidomethyl)-1-methyl-1,3,4,9-tetrahydropyrano[3,4-b]indole
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | Tryptophol | HCID 10685 | — |
| Edukt | 7-Ethyltryptophol | HCID 198231 | — |
| Edukt | 5-Benzyloxy-3-(2-hydroxyethyl)indole | HCID 744849 | — |
| Edukt | N-[(7-methoxy-1,3,4,9-tetrahydro-1-methylpyrano-[3,4-b]indol-1-yl)methyl]-acetamide | HCID 20485044 | — |
| Edukt | N-[(8-ethyl-1,3,4,9-tetrahydro-1-methylpyrano[3,4-b]indol-1-yl)methyl]-acetamide | HCID 20485069 | — |
| Edukt | 2-(6-Methoxy-1h-indol-3-yl)ethanol | HCID 20485101 | — |
| Edukt | N-[(6-phenylmethoxy-1,3,4,9-tetrahydro-1-methylpyrano[3,4-b]indol-1-yl)methyl]-acetamide | HCID 20485103 | — |
| Produkt | 1-(Acetamidomethyl)-1-methyl-1,3,4,9-tetrahydropyrano[3,4-b]indole | HCID 12708180 | — |
Reaktionsschritte
In the same manner but replacing indole-3-ethanol with an equivalent amount of 7-ethylindole-3-ethanol, 6-methoxyindole-3-ethanol or 5-phenylmethoxy-indole-3-ethanol, the following compounds of formula IIa are obtained, respectively: N-[(8-ethyl-1,3,4,9-tetrahydro-1-methylpyrano[3,4-b]indol-1-yl)methyl]-acetamide, N-[(7-methoxy-1,3,4,9-tetrahydro-1-methylpyrano-[3,4-b]indol-1-yl)methyl]-acetamide and N-[(6-phenylmethoxy-1,3,4,9-tetrahydro-1-methylpyrano[3,4-b]indol-1-yl)methyl]-acetamide.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US04409224 |
| Quelldatensatz | uspto-grants-1983_10 |
| ORD ID | ord-cf108d1e3bac41459f0d9bd66c321af4 |
| Quellennotiz | uspto-grants-1983_10 |