HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Thiophenol → N-{4-[2-Amino-3,5-dicyano-6-(phenylsulphanyl)-4-pyridinyl]phenyl}acetamide
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | Thiophenol | HCID 7969 | — |
| Edukt | Malononitrile | HCID 8010 | — |
| Edukt | Triethylamine | HCID 8471 | — |
| Edukt | N-(4-(2,2-Dicyanoethenyl)phenyl)acetamide | HCID 33296 | — |
| Lösungsmittel | Ethanol | HCID 702 | — |
| Produkt | N-{4-[2-Amino-3,5-dicyano-6-(phenylsulphanyl)-4-pyridinyl]phenyl}acetamide | HCID 12016387 | — |
Reaktionsschritte
19 g (0.09 mol) of N-[4-(2,2-dicyanovinyl)phenyl]acetamide, 5.95 g (0.09 mol) of malononitrile and 9.91 g (0.09 mol) of thiophenol are initially charged in 120 ml of ethanol, and 0.4 ml of triethylamine are added. The mixture is stirred at reflux for 2 h, during which the product crystallizes. After cooling, the product is filtered off with suction and dried under reduced pressure.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US07135486B1 |
| Quelldatensatz | uspto-grants-2006_11 |
| ORD ID | ord-9db1f65e28f44eb980bc6e416322f632 |
| Quellennotiz | uspto-grants-2006_11 |