HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
1-(2-benzyloxyethyl)-4-[(4-ethylphenyl)methyl]-3-(beta-D-glucopyranosyloxy)-5-methyl-1H-pyrazole → 2-(5-Methyl-pyrazol-1-YL)-ethanol
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | 1-(2-benzyloxyethyl)-4-[(4-ethylphenyl)methyl]-3-(beta-D-glucopyranosyloxy)-5-methyl-1H-pyrazole | HCID 69133733 | — |
| Katalysator | HCID 178418390 | HCID 178418390 | — |
| Lösungsmittel | Ethanol | HCID 702 | — |
| Produkt | 2-(5-Methyl-pyrazol-1-YL)-ethanol | HCID 12360320 | 372,5% |
Reaktionsschritte
To a solution of 1-(2-benzyloxyethyl)-4-[(4-ethylphenyl)methyl]-3-(β-D-glucopyranosyloxy)-5-methyl-1H-pyrazole (0.012 g) in ethanol (2 mL) was added a catalytic amount of 10% palladium-carbon powder, and the mixture was stirred at room temperature under a hydrogen atmosphere for 30 minutes. Insoluble materials were removed by filtration, and the solvent was removed under reduced pressure to give 4-[(4-ethylphenyl)methyl]-3-(β-D-glucopyranosyloxy)-1-(2-hydroxyethyl-5-methyl-1H-pyrazole (0.011 g).
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US07087579B2 |
| Quelldatensatz | uspto-grants-2006_08 |
| ORD ID | ord-061bca7ca0d24355a6d61c73b9464cfc |
| Quellennotiz | uspto-grants-2006_08 |