HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Sodium Sulfate → Methyl 4-amino-o-anisate
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | Sodium Sulfate | HCID 24436 | — |
| Edukt | Methyl 2-methoxy-4-nitrobenzoate | HCID 10798535 | — |
| Katalysator | Palladium | HCID 23938 | — |
| Lösungsmittel | Methanol | HCID 887 | — |
| Produkt | Methyl 4-amino-o-anisate | HCID 168705 | 100,3% |
Reaktionsschritte
The hydrogenation of methyl 2-methoxy-4-nitrobenzoate (700 mg, 3.3 mmol) in methanol (10 mL) catalyzed by 5% Pd—C (100 mg) and Na2SO4 (100 mg) at 50 psi for 1 h gave methyl 4-amino-2-methoxybenzoate (600 mg, quant.) as a white solid.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US08835430B2 |
| Quelldatensatz | uspto-grants-2014_09 |
| ORD ID | ord-291ccf0f56bf4b08a8b320f9ee99d538 |
| Quellennotiz | uspto-grants-2014_09 |