HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
tert-Butyl hydroperoxide → HCID 19050660, Verbindung
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | tert-Butyl hydroperoxide | HCID 6410 | — |
| Edukt | HCID 19050670 | HCID 19050670 | — |
| Katalysator | Dicobalt Octacarbonyl (stabilized with 1-5% Hexane) | HCID 25049 | — |
| Lösungsmittel | Acetonitrile | HCID 6342 | — |
| Produkt | HCID 19050660 | HCID 19050660 | — |
Reaktionsschritte
A solution of 100 mg of N-methyl 3-phenyl-5-(4,6-dimethoxy-2-pyrimidinylmethyl)-4-isoxazolecarboxanilide, 20 mg of dicobalt octacarbonyl, and 1 ml of t-butylhydroperoxide, in 60 ml of acetonitrile is refluxed for 48 hours. An additional 1 ml of t-butylhydroperoxide is added after 12 hrs and 24 hrs. Thin layer chromatography after 48 hrs indicates the presence of starting material and the title compound.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US05561101 |
| Quelldatensatz | uspto-grants-1996_10 |
| ORD ID | ord-776e651b363d4802847ce5c4cfead691 |
| Quellennotiz | uspto-grants-1996_10 |