HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Benz(a)anthracene, 4-bromo- → 4-(Benz[a]anthracen-4-yl)benz[a]anthracene
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | Benz(a)anthracene, 4-bromo- | HCID 182324 | — |
| Edukt | 9-Bromo-10-(naphthalen-2-yl)anthracene | HCID 16116263 | — |
| Produkt | 4-(Benz[a]anthracen-4-yl)benz[a]anthracene | HCID 59412552 | — |
Reaktionsschritte
Preparation analogous to Example 7. 9-Bromo-10-(2-naphthyl)anthracene is replaced by 15.4 g (50 mmol) of 4-bromobenz[a]anthracene. Recrystallisation four times from o-dichlorobenzene (about 15 ml/g); sublimation (p=5×10−5 mbar, T=320° C.). Yield: 16.8 g (37 mmol), 74.0%, purity 99.9% (HPLC), Tg=130.3° C.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US08986852B2 |
| Quelldatensatz | uspto-grants-2015_03 |
| ORD ID | ord-0bb428719fc3407f87a98082a44a6125 |
| Quellennotiz | uspto-grants-2015_03 |