RuPhos Pd G3

HCID 117064724CAS 1445085-77-7

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Basic information

Standard SMILES
CC(C)Oc1cccc(OC(C)C)c1-c1ccccc1P(C1CCCCC1)C1CCCCC1.CS(=O)(=O)O.Nc1ccccc1-c1[c-]cccc1.[Pd]
InChIKey
GYTUQNMMIUJBSP-UHFFFAOYSA-N
Molecular formula
C43H57NO5PPdS-
Average molar mass
837.3751 g/mol

Names & identifiers

Preferred name
RuPhos Pd G3
English name
RuPhos Pd G3
Molecular formula
C43H57NO5PPdS-
Molecular weight
837.375141

Names & synonyms

RuPhos-Pd-G3methanesulfonato(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(ii)Methanesulfonato(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)RuPhos Palladacycle Gen.3RuPhos-G3-PalladacycleRuPhos Pd G3RuPhos Pd G3 95%RuPhos Pd G3 ChemBeadsRuPhos Pd G3 ISO 9001：2015 REACHMethanesulfonato(2-dicyclohexylphosphino-2',6'-di-i-propoxy-...

Database identifiers

CAS
1445085-77-7
PubChem CID
117064724
EC Number
809-028-5

Properties

Physicochemical properties

Melting point
188 · 188-196°C (decomposition)
storage temp.
2 · under inert gas (nitrogen or Argon) at 2–8 °C
form
Powder
color
white
InChIKey
GYTUQNMMIUJBSP-UHFFFAOYSA-N
SMILES
CS(=O)(=O)O[Pd]c1ccccc1-c2ccccc2N.CC(C)Oc3cccc(OC(C)C)c3-c4ccccc4P(C5CCCCC5)C6CCCCC6

Safety & regulation

Safety data

wgk
3
risk_code
36/37/38-52/53
Signal word
Warning
Symbol(GHS)
GHS07
hazard_code
Xi
safety_code
26-61

Chemistry & industry

Applications · 2 items

UsesRuPhos Pd G3 can be used as a pre-catalyst in the following protocols:Palladium-catalyzed Suzuki coupling of 5-p-toluenesulfonyltetrazoles with arylboronic acids to synthesize 1,5-disubstituted tetrazoles.Suzuki-Miyaura catalyst-transfer polycondensation (SCTP) of 3-alkylthiophenes in the presence of N-methylimidodiacetic (MIDA)-boronate monomers.Suzuki-Miyaura-cross-coupling of aminothiophenes.

General DescriptionRuPhos Pd G3 is a third generation (G3) Buchwald precatalyst that can be used in cross-coupling reactions for the formation of C-C, C–N, C–O, C–F, C–CF3, and C–S bonds. It is air-, moisture-, and thermally-stable and is highly soluble in a wide range of common organic solvents. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.

Upstream & downstream products

Suppliers50 total

新乡市润宇新材料科技有限公司15690792173 · [email protected]
武汉敬康恩生物医药科技有限公司13720134139 086-15871494362 13720134139 · [email protected]
上海毕合生物化学技术有限公司13816464724 · [email protected]
上海毕得医药科技股份有限公司400-1647117 13681763483 · [email protected]
上海遐瑞医药科技有限公司+86-021-61551413 · [email protected]

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