Basic information
- Standard SMILES
C[S+](C)[BH2-]Cl- InChIKey
CUKLQTNDSCOWTI-UHFFFAOYSA-N- Molecular formula
- C2H9BClS
- Average molar mass
- 111.41 g/mol
Names & identifiers
- Preferred name
- BORON MONOCHLORIDE-METHYL SULFIDE COMPLEX
- English name
- BORON MONOCHLORIDE-METHYL SULFIDE COMPLEX
- Molecular formula
- C2H9BClS
- Molecular weight
- 111.41
Names & synonyms
Chloroborane methylMONOCHLOROBORANE-METHYLSULFIDEMonochloroborane-dimethyl sulfideCHLOROBORANE-METHYL SULFIDE COMPLEXChloro(dimethyl sulfide)dihydroboronMonochloroborane-dimethyl sulfide (1:1)Chloroborane-methyl sulfide 1:1 complexMONOCHLOROBORANE-METHYL SULFIDE COMPLEXMonochloroborane-dimethylsulfide complexBORON MONOCHLORIDE-METHYL SULFIDE COMPLEX
Database identifiers
- CAS
63348-81-2
Properties
Physicochemical properties
- Density
- 1.059 g/mL · 1.059 g/mL at 25 °C (lit.)
- Flash point
- 76 °F · 76 °F
- solubility
- soluble in Benzene, Chloroform
- form
- Oil
- color
- Clear Colourless
- Stability
- Hygroscopic, Moisture Sensitive
- InChI
- 1S/C2H8BClS/c1-5(2)3-4/h3H2,1-2H3
- InChIKey
- CUKLQTNDSCOWTI-UHFFFAOYSA-N
- SMILES
- C[S+](C)[BH2-]Cl
- UNSPSC Code
- 12352101 · 12352101
- NACRES
- 22 · NA.22
- Symbol(GHS)
- 2 · GHS02,GHS05
- Signal word
- Danger
- Hazard statements
- 226 · H226-H314
- Precautionary statements
- 210 · P210-P233-P240-P280-P303+P361+P353-P305+P351+P338
- PPE
- Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
- Hazard Codes
- C
- Risk Statements
- 10 · 10-14-34
- Safety Statements
- 16 · 16-26-27-36/37/39-45
- RIDADR
- 2920 · UN 2920 8/PG 2
- WGK Germany
- 3 · 3
- HazardClass
- 3.2 · 3.2
- PackingGroup
- III
- Storage Class
- 3 · 3 - Flammable liquids
- Hazard Classifications
- 3 Skin · Flam. Liq. 3Skin Corr. 1B
- Limited Quantities
- 1 L · 1.0 L (0.3 gallons) (liquid) or 1 Kg (2.2 lbs) (solid)
- Excepted Quantities
- Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)
Safety & regulation
Safety data
- PPE
- Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
- wgk
- 3
- ridadr
- UN 2920 8/PG 2
- risk_code
- 10-14-34
- Signal word
- Danger
- Symbol(GHS)
- GHS02,GHS05
- hazard_code
- C
- safety_code
- 16-26-27-36/37/39-45
- hazard_class
- 3.2
- Storage Class
- 3 - Flammable liquids
- packing_group
- III
- Hazard statements
- H226-H314
- Limited Quantities
- 1.0 L (0.3 gallons) (liquid) or 1 Kg (2.2 lbs) (solid)
- Excepted Quantities
- Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)
- Hazard Classifications
- Flam. Liq. 3Skin Corr. 1B
- Precautionary statements
- P210-P233-P240-P280-P303+P361+P353-P305+P351+P338
Chemistry & industry
Applications
UsesReactant for:Substitution reactionsBoronation reactionsPreparation of diborylaminesPreparation of unsymmetrical borafluorenes via low-temperature carbon-hydrogen activation reactionsAsymmetrical aldol reactions with a-chiral aldehydesAddition reaction with α-pinene
Preparation methods
PreparationMonochloroborane-dimethyl sulfide is prepared by redistribution of Borane-Dimethyl Sulfide (BMS) and Boron Trichloride. SMe2 and by the reaction of BMS with CCl4. The reagent is in equilibrium with approximately 15% each of BHCl2.SMe2 and BMS.
Suppliers24 total
Dayang Chem (Hangzhou) Co.,Ltd.+86-0571-88938639 17705817739 · [email protected]
安耐吉化学&3A（安徽泽升科技有限公司）021-58432009 400-005-6266 · [email protected]
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Sigma-Aldrich西格玛奥德里奇(上海)贸易有限公司021-61415566 800-8193336 · [email protected]
Alfa Chemistry+1-5166625404 · [email protected]
艾吉析科技（上海）有限公司17721401538;17717235263 17721401538 · [email protected]
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金锦乐(湖南)化学有限公司18001959627(微信同号) 18001959627 · [email protected]
杭州洁汉化工有限公司+86-571-86217390; +8618058761490 · [email protected]
career henan chemical co+86-0371-86658258 · [email protected]
广东翁江化学试剂有限公司0751-2815688 13927872512 · [email protected]
Aladdin Scientific[email protected]
广东元丰化学试剂有限公司0751-2829979 13318584237 · [email protected]
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上海齐奥化工科技有限公司021-58892003 · [email protected]
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宝鸡缔都医药化工有限公司029-029-81148929 17792602132 · [email protected]
Related reactions
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