HuagongsheHuagongshe Chemistry Print Report · For research reference only
Bentazon
BENTAZON · GALAXY · leader · Bendioxide · BASAGRAN · 3-isopropyl-1h-2,1,3-benzothiadiazin-4(3h)-one-2,2-dioxide · 3,4-Dihydro-3-isopropyl-1H-2,1,3-benzothiadiazin-4-one 2,2-Dioxide · laddok
Identifiers & Physical Properties
| CAS No. | 25057-89-0 |
|---|---|
| Molecular formula | C10H12N2O3S |
| Average molar mass | 240.28 g/mol |
| Monoisotopic mass | 240.05686324 g/mol |
| SMILES | CC(C)N1C(=O)c2ccccc2NS1(=O)=O |
| InChIKey | ZOMSMJKLGFBRBS-UHFFFAOYSA-N |
| PubChem CID | 2328 |
| ChEMBL | CHEMBL1567045 |
| ChEBI | CHEBI:3018 |
| EC No. | 246-585-8 |
| DTXSID | DTXSID0023901 |
Chemical & Physical Properties
| XLogP | 2.8 |
|---|---|
| Topological polar surface area | 74.9 |
| Hydrogen bond donors | 1 |
| Hydrogen bond acceptors | 4 |
| Rotatable bonds | 1 |
| Heavy atoms | 16 |
| Formal charge | 0 |
| Complexity | 385 |
| SpringerMaterials Properties | Fusion temperature |
| Pesticides | Pesticide -> EPA IRISAgrochemicals -> Pesticide active substancesActive substance -> EU Pesticides database: ApprovedPesticides -> Herbicides, OtherEnvironmental transformation -> Pesticides (parent, predecessor) |
| LogP (partition coefficient) | log Kow = 2.34-0.46 |
| Odor | Odorless |
| Density | 1.41 at 20 °C1.3387 (rough estimate) |
| Color/Form | Colorless crystalstech. is an ochre-yellow solid [White, crystalline powder |
| Solubility | Solubility: xylene < 1 g/100 g (at 20 °C). /Technical bentazon/In water, 500 mg/L at 20 °CIn water 570 mg/L (pH 7, 20 °C)In acetone 1507, ethanol 861, ethyl acetate 650, diethyl ether 616, chloroform 180, benzene 33, cyclohexane 0.2 (all in g/kg, 20 °C)Solubility at 20 °C in xylene <1 g/100gcyclohexanone approx 18 g/100gSolubility in water: noneChloroform (Slightly), Methanol (Slightly)0.5g/L(20 ºC) |
| Corrosivity | Not corrosive |
| Human Drugs | Pharmaceuticals |
| Decomposition | When heated to decomposition it emits very toxic fumes of /sulfur oxides and nitrogen oxides/.200 °C |
| Melting point | 139.7 °CDecomposition temp: 200 °C137-139 °C137-139°C |
| Vapor pressure | 0.00000345 [mmHg]4.05X10-8 mm Hg at 20 °CVapor pressure, Pa at 20 °C: |
| Boiling point | 395.7±25.0 °C(Predicted) |
| Refractive index | 1.5650 (estimate) |
| Flash point | 2 °C |
| Storage conditions | APPROX 4°C |
| Physical state | Solid |
| pKa (acidity coefficient) | pKa (24°): 3.3 |
| Color | White |
| Merck | 13,1051 |
| BRN | 530220 |
| Henry's law constant | 4.5×103 mol/(m3Pa) at 25℃, HSDB (2015) |
| Major applications | agricultureenvironmental |
| InChI | 1S/C10H12N2O3S/c1-7(2)12-10(13)8-5-3-4-6-9(8)11-16(12,14)15/h3-7,11H,1-2H3 |
| InChIKey | ZOMSMJKLGFBRBS-UHFFFAOYSA-N |
| SMILES | CC(C)N1C(=O)c2ccccc2NS1(=O)=O |
| EWG's Food Scores | 1-3 |
| FDA UNII | R4S7ZGZ9CT |
| NIST Chemistry Reference | Bentazone(25057-89-0) |
| EPA Substance Registry System | Bentazon (25057-89-0) |
| UNSPSC Code | 41116107 |
| NACRES | NA.24 |
| GHS pictogram | GHS07 |
| Signal word | Warning |
| GHS hazard statements | H302-H317-H319-H412 |
| GHS precautionary statements | P261-P273-P280-P301+P312-P302+P352-P305+P351+P338 |
| Personal protective equipment (PPE) | dust mask type N95 (US), Eyeshields, Faceshields, Gloves |
| Hazard symbols | Xn,F |
| Risk statements (R) | 22-36-43-52/53-20/21/22-11 |
| Safety statements (S) | 2-24-37-61-36-26-16 |
| UN transport number | UN 1648 3/PG 2 |
| Water hazard class (WGK) | 2 |
| RTECS number | DK9900000 |
| TSCA inventory status | TSCA listed |
| Customs code | 29349990 |
| Storage class | 11 - Combustible Solids |
| Hazard class | Acute Tox. 4 OralEye Irrit. 2Repr. 2Skin Sens. 1 |
| Hazardous substances data | 25057-89-0(Hazardous Substances Data) |
| Toxicity | LD50 in male, female rats (mg/kg): 383.2, 433.6 orally (Ugazio) |
Safety & Regulations
| GHS classification | WarningH302: Harmful if swallowed [Warning Acute toxicity, oral]P203, P261, P264, P264+P265, P270, P272, P280, P301+P317, P302+P352, P305+P351+P338, P318, P321, P330, P333+P317, P337+P317, P362+P364, P405, and P501 (click each P-code to see the statement)H302 (100%): Harmful if swallowed [Warning Acute toxicity, oral]P203, P261, P264, P264+P265, P270, P272, P273, P280, P301+P317, P302+P352, P305+P351+P338, P318, P321, P330, P333+P317, P337+P317, P362+P364, P405, and P501 (click each P-code to see the statement) |
|---|---|
| Regulatory information | Hazard Traits - Hepatotoxicity and Digestive System ToxicityRegulation (EC) No 396/2005 (amended)00/68/EC, 2010/77/EU, Reg. (EU) 2015/1885, Reg. (EU) 2016/549, Reg. (EU) 2017/841, Reg. (EU) 2018/660, Reg. (EU) 2020/1093, Reg. (EU) No 540/2011Bentazone: Does not have an individual approval but may be used under an appropriate group standard |
| Fire hazards | Liquid formulations containing organic solvents may be flammable. Gives off irritating or toxic fumes (or gases) in a fire. Risk of fire and explosion if formulations contain flammable/explosive solvents. |
| Hazards summary | An eye irritant[ICSC] A mucous membrane irritant[HSDB] May cause skin sensitization[eChemPortal: ESIS] An eye irritant[MSDSonline] Not likely to be carcinogenic to humans (Group NL)[EPA] |
| EC classification | Symbol: XnR: 22-36S: (2)-24-37-61 |
| Special Reports | USEPA/Office of Prevention, Pesticides and Toxic SubstancesReregistration Eligibility Decision Document for Bentazon EPA 738-R-94-029 (September 1994). The RED summarizes the risk assessment conclusions and outlines any risk reduction measures necessary for the pesticide to continue to be registered in the USA.[Available from, as of October 26, 2017: http://www.epa.gov/pesticides/reregistration/status.htm]WHO/IPCSPesticide Residues in Food - 1991. Part II - Toxicology (1992) |
| FIFRA requirements | Tolerances are established for the combined residues of the herbicide bentazon (3-isopropyl-1H-2,1,3-benzothiadiazin-4(3H)-one-2,2-dioxide) and its 6- and 8-hydroxy metabolites in or on the following food commodities:[Table#4591]Tolerances are established for the combined residues of the herbicide bentazon (3-isopropyl-1H-2,1,3-benzothiadiazin-4(3H)-one-2,2-dioxide) and its metabolite 2-amino-N-isopropyl benzamide (AIBA) in or on the following food commodities:[Table#4592]Tolerances with regional registration as defined in section 180.1(m), are established for combined residues of the herbicide, bentazon (3-isopropyl-1H-2, 1,3-benzothiadiazin-4(3H)-one-2,2-dioxide) and its 6- and 8-hydroxy metabolites in or on the following food commodities:[Table#4593]Based on the reviews of the generic data for the active ingredient bentazon, the Agency has sufficient information on the health effects of bentazon and on its potential for causing adverse effects in fish and wildlife and the environment. Therefore, the Agency concludes that products containing bentazon for all uses are eligible for reregistration. The Agency has determined that bentazon products, labeled and used as specified in this Reregistration Eligibility Decision, will not pose unreasonable risks or adverse effects to humans or the environment.As the federal pesticide law FIFRA directs, EPA is conducting a comprehensive review of older pesticides to consider their health and environmental effects and make decisions about their continued use. Under this pesticide reregistration program, EPA examines newer health and safety data for pesticide active ingredients initially registered before November 1, 1984, and determines whether the use of the pesticide does not pose unreasonable risk in accordance to newer safety standards, such as those described in the Food Quality Protection Act of 1996. Bentazon is found on List A, which contains most pesticides that are used on foods and, hence, have a high potential for human exposure. List A consists of the 194 chemical cases (or 350 individual active ingredients) for which EPA issued registration standards prior to FIFRA '88. Case No: 0182Pesticide type: HerbicideRegistration Standard Date: 09/28/85Case Status: RED Approved 09/94OPP has made a decision that some/all uses of the pesticide are eligible for reregistration, as reflected in a Reregistration Eligibility Decision (RED) document.Active ingredient (AI): Sodium bentazonData Call-in (DCI) Date(s): 08/29/90AI Status: OPP has completed a Reregistration Eligibility Decision (RED) document for the case/AI. |
| Chemical Dangers | Decomposes on heating and on burning. This produces toxic fumes including sulfur oxides and nitrogen oxides. |
| Packaging and Labelling | Do not transport with food and feedstuffs. |
| Toxic Combustion Products | Special hazards arising from the substance or mixture: Carbon oxides, nitrogen oxides (NOx), sulfur oxides. |
| Hazard Classes and Categories | Acute Tox. 4 (100%)Acute toxicity - category 4Repr. 2 |
| State Drinking Water Standards | (CA) CALIFORNIA 18 ug/L |
| State drinking water guidelines | (WI) WISCONSIN 300 ug/L |
| Fire fighting | Use water spray, powder, foam, carbon dioxide. |
| First aid measures | Fresh air, rest. Refer for medical attention.Remove contaminated clothes. Rinse and then wash skin with water and soap.First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.Give one or two glasses of water to drink. Refer for medical attention . |
| Safe storage | Provision to contain effluent from fire extinguishing. Separated from food and feedstuffs. |
| Fire fighting procedures | Suitable extinguishing media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.Wear self contained breathing apparatus for fire fighting if necessary. |
| Storage conditions | Keep container tightly closed in a dry and well-ventilated place. |
| Cleanup methods | ACCIDENTAL RELEASE MEASURES: Personal precautions, protective equipment and emergency procedures: Use personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. Environmental precautions: Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Methods and materials for containment and cleaning up: Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal. |
| Disposal methods | SRP: Recycle any unused portion of the material for its approved use or return it to the manufacturer or supplier. Ultimate disposal of the chemical must consider: the material's impact on air qualitypotential migration in air, soil or watereffects on animal, aquatic and plant lifeand conformance with environmental and public health regulations. If it is possible or reasonable use an alternative chemical product with less inherent propensity for occupational harm/injury/toxicity or environmental contamination.Product: Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste disposal service to dispose of this materialContaminated packaging: Dispose of as unused product.Group I Containers: Combustible containers from organic or metallo-organic pesticides (except organic mercury, lead, cadmium, or arsenic compounds) should be disposed of in pesticide incinerators or in specified landfill sites. /Organic or metallo-organic pesticides/Group II Containers: Non-combustible containers from organic or metallo-organic pesticides (except organic mercury, lead, cadmium, or arsenic compounds) must first be triple-rinsed. Containers that are in good condition may be returned to the manufacturer or formulator of the pesticide product, or to a drum reconditioner for reuse with the same type of pesticide product, if such reuse is legal under Department of Transportation regulations (eg 49 CFR 173.28). Containers that are not to be reused should be punctured ... and transported to a scrap metal facility for recycling, disposal or burial in a designated landfill. /Organic or metallo-organic pesticides/ |
| Spillage disposal | Do NOT wash away into sewer. Sweep spilled substance into covered containers. If appropriate, moisten first to prevent dusting. Carefully collect remainder. Then store and dispose of according to local regulations. Personal protection: chemical protection suit including self-contained breathing apparatus. |
| Preventive Measures | ACCIDENTAL RELEASE MEASURES: Personal precautions, protective equipment and emergency procedures: Use personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. Environmental precautions: Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.Precautions for safe handling: Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed.Appropriate engineering controls: Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.For more Preventive Measures (Complete) data for Bentazon (6 total), please visit the HSDB record page. |
| Eye Prevention | Wear safety goggles. |
| Inhalation Risk | Evaporation at 20 °C is negligiblea harmful concentration of airborne particles can, however, be reached quickly on spraying or when dispersed, especially if powdered. |
| Skin Prevention | Protective gloves. |
| Interactions | Maize black Mexican sweet cell suspension cultures were used to study the effects of various cytochrome p450 monooxygenase inhibitors on the uptake and metabolism of the herbicide bentazon. Maize cells rapidly absorbed bentazon and metabolized it via aryl hydroxylation and glycosylation to a glycosyl conjugate of 6-hydroxybentazon. Maize black Mexican sweet cells accumulated bentazon to levels approximately 20 fold greater than those in the external medium. When maize black Mexican sweet cells were incubated in an external medium containing 25 uM bentazon, the formation of the glycosyl conjugate (ca 2 nmol/min/g fresh wt) was rate limited by aryl hydroxylation. Tetcyclacis, a plant growth retardant, phenylhydrazine, a mechanism based cytochrome p450 inhibitor, and piperonyl butoxide, an insecticide synergist, inhibited bentazon metabolism with I50 values of approximately 0.1, 1.0, and 1.0 uM, respectively. Other mechanism based cytochrome p450 inhibitors, 3(2,4-dichlorophenoxy)-1-propyne and aminobenzotriazole, also inhibited bentazon metabolism but were less effective. The results obtained with selected inhibitors are consistent with the hypothesis that aryl hydroxylation of bentazon is catalyzed by a cytochrome p450 monooxygenase. |
| Target organs | Hematologic |
| Ecotoxicity values | LC50Species: Colinus virginianus (Northern Bobwhite Quail) juveniledietary >10000 ppm for 8 days /42% purity/Species: Eisenia fetida (Earthworm) adult, sexually maturedermal, filter paper 3.27 kg/ha for 48 hr (95% confidence interval: 2.50-4.28 kg/ha)EC50Species: Nostoc muscorum (Blue-Green Algae) Axenic clonal stockConditions: freshwater, static, 28 °CConcentration: 1 mM for 72 hrEffect: physiology, decreased photosynthesisConcentration: 6.8 mM for 72 hrEffect: biochemistry, decreased phycobiliproteinsFor more Ecotoxicity Values (Complete) data for Bentazon (23 total), please visit the HSDB record page. |
| Environmental fate | TERRESTRIAL FATE: Based on a classification scheme(1), a Koc range of 0 to 46(2,3) indicates that bentazon is expected to have very high to high mobility in soil(SRC). The pKa of bentazon is 3.3(4), indicating that this compound will exist almost entirely in anion form in the environment and anions generally do not adsorb more strongly to soils containing organic carbon and clay than their neutral counterparts(5). Volatilization from moist soil is not expected because the compound exists as an anion and anions do not volatilize. Bentazon is not expected to volatilize from dry soil surfaces(SRC) based upon a vapor pressure of 4.05X10-8 mm Hg at 20 °C(2). In aerobic soils, reported degradation half-lives of 6.7 to 50 days(2,6) suggests that under certain conditions biodegradation may be an important environmental fate process in soil(SRC).FIELD STUDY: Field dissipation studies were conducted in Texas on sandy soil (0.5% OM) planted with peanuts, Mississippi on a Commerce silt loam soil planted with soybeans and peanuts, Mississippi on a Sharkey silty clay loam soil planted with soybeans, North Carolina on acidic, sandy loam soil (2.8% OM) planted to peanuts, Minnesota on clay soil planted to soybeans, and Idaho on a sandy loam soil. Bentazon, applied as a wettable powder or soluble concentrate at cumulative rates of 1.0 to 10 lbs a.i./A, had field dissipation half-lives of 7 to 33 days. The degradate AIBA was detected (< 0.05 ppm) in the North Carolina, Mississippi, Alabama, and Idaho field dissipation studies. Bentazon and 2-amino-N-isopropylbenazamide were not detected in deep soil samples (> 12 inches of soil) in field studies.AQUATIC FATE: Based on a classification scheme(1), a Koc range of 0 to 46(2,3) indicates that bentazon is not expected to adsorb to suspended solids and sediment(SRC). A pKa of 3.3(4) indicates bentazon will exist almost entirely in the anion form at pH values of 5 to 9 and, therefore, volatilization from water surfaces is not expected to be an important fate process(SRC). According to a classification scheme(5), a whole body BCF of 3.7 in bluegill sunfish(6), suggests the potential for bioconcentration in aquatic organisms is low(SRC). Complete photolysis of bentazon took place within 16 hours in distilled water at pH 6.8 when irradiated with UV light(7,8). Bentazon was not degraded in biodegradation experiments anaerobic aquifer conditions(9) but the available soil studies would suggest that biodegradation may an important environmental fate process in water.(SRC).ATMOSPHERIC FATE: According to a model of gas/particle partitioning of semivolatile organic compounds in the atmosphere(1), bentazon, which has a vapor pressure of 4.05X10-8 mm Hg at 20 °C(2), is expected to exist solely in the particulate phase in the ambient atmosphere. Particulate-phase bentazon may be removed from the air by wet and dry deposition(SRC). Bentazon absorbs light at wavelengths between 330 and 335 nm(3) and, therefore, may be susceptible to direct photolysis by sunlight, since sunlight consists of wavelengths above 290 nm(SRC). |
| Food survey values | Bentazon was not included in the U.S Food and Drug Administration Total Diet Study Market Baskets 2004 through 2005(1). |
| Adverse effects | Skin Sensitizer - An agent that can induce an allergic reaction in the skin. |
| Exposure routes | The substance can be absorbed into the body by inhalation and by ingestion. |
| Milk Concentrations | In 2010, bentazone was not detected in bovine raw milk (n=100) from a local farm, and full-fat milk (n=30), half-skimmed milk (n=20), and skimmed milk (n=20) from a local supermarket, near Shenyang Agricultural University, China(1). |
| Toxicity summary | IDENTIFICATION AND USE: Bentazone is a white, crystalline solid. It was formerly used as an herbicide. HUMAN STUDIES: Bentazone is irritating to eyes and mucous membranes. A 50-year-old male who had sprayed corn with a solution of bentazone was admitted to the hospital with sweating, fever, nausea, vomiting of aqueous and hemorrhagic content, and bloody, watery stools. He was treated according to the symptoms including extracorporeal hemodialysis, but eventually suffered from multiorgan failure (acute respiratory failure, acute liver failure, coagulopathy, acute renal failure, metabolic acidosis, and gastrointestinal bleeding) and died 11.35 hr after admittance. In another case, intentional poisoning with 130 g of bentazone resulted in vomiting, fever, sweating, pipe-like muscle rigidity, sinus tachycardia, drowsiness, leukocytosis, rhabdomyolysis and hepatorenal damage. ANIMAL STUDIES: Bentazone is not a skin irritant but was a moderate eye irritant in rabbits. It is a skin sensitizer in guinea-pigs. In a chronic toxicity study, bentazone was administered to rats (50 of each sex per group) via a diet at doses 0, 5, 17 and 76 mg/kg bw per day for 2 years. Statistical analysis of tumor incidence did not reveal any significance among the groups tested. Bentazone was not teratogenic in rabbits or rats. In rat developmental studies, it increased post-implantation loss, skeletal variations (incomplete or absent ossification in the phalangeal nuclei of the extremities, sternebrae and cervical vertebrae) and reduced body weights of fetuses surviving to day 21 at 250 mg/kg bw per day. Dietary administration of bentazone to rats at dose levels of 0, 300, 1000 and 3500 ppm did not result in any indication of neurotoxicity. In vitro genotoxicity studies included bacterial reverse mutation assays on Salmonella typhimurium and Escherichia coli, DNA damage and repair studies on E. coli and Saccharomyces cerevisiae, and chromosomal aberration and forward mutation assays in CHO cells. In vivo studies included chromosome analyses in mice and rats, unscheduled DNA synthesis tests in mice, and mutation assays in germ cells for mice and rats. Bentazone gave negative results in all of these studies. ECOTOXICITY STUDIES: Bentazone affected zebrafish embryos and associated bacterial communities. It was nontoxic to bees. |
| Ecotoxicity excerpts | /AQUATIC SPECIES/ This study aimed to assess the effects of Basagran on zebrafish (Danio rerio) embryos. The embryos were exposed to Basagran at concentrations ranging from 120.0 to 480.6 mg/L, and the effects on embryo development (up to 96 hr) and bacterial communities of 96 hr-larvae were assessed. The embryo development response was time-dependent and concentration-dependent (106.35 < EC50 < 421.58 mg/L). The sensitivity of embryo-related endpoints decreased as follows: blood clotting in the head and/or around the yolk sac > delay or anomaly in yolk sac absorption > change in swimming equilibrium > development of pericardial and/or yolk sac edema > scoliosis. A PCR-DGGE analysis was used to evaluate changes in the structure, richness, evenness and diversity of bacterial communities after herbicide exposure. A herbicide-induced structural adjustment of bacterial community was observed. In this study, it was successfully demonstrated that Basagran affected zebrafish embryos and associated bacterial communities, showing time-dependent and concentration-dependent embryos' developmental response and structural changes in bacterial community. Thus, this work provides for the first time a complementary approach, which is useful to derive robust toxicity thresholds considering the embryo-microbiota system as a whole. The aquatic hazard assessment will be strengthened by combining current ecotoxicological tests with molecular microbiology tools./OTHER TERRESTRIAL SPECIES/ /Nontoxic to bees.//OTHER TOXICITY INFORMATION/ The toxicological effects of the active ingredients of the herbicides diuron and bentazon on the activity of acetylcholinesterase (AChE) of krait (Bungarus sindanus) venom and electric eel (Electrophorus electricus) were studied. The diuron and bentazon caused non-competitive inhibition of AChE from both species. For the venom AChE, the calculated IC50 for diuron and bentazon were found to be 3.25 and 0.14 uM, while for eel AChE, the respective IC50 values were 3.6 and 0.135 uM. In comparison, bentazon was a more potent inhibitor than diuron of AChE from both species. The insecticide lindane did not have any inhibitory effect on AChE activity in either species, even when tested at high concentrations (200-800 uM). |
| Signs and Symptoms | Redness. Pain. |
| Ongoing Test Status | EPA has released the Interactive Chemical Safety for Sustainability (iCSS) Dashboard. The iCSS Dashboard provides an interactive tool to explore rapid, automated (or in vitro high-throughput) chemical screening data generated by the Toxicity Forecaster (ToxCast) project and the federal Toxicity Testing in the 21st century (Tox21) collaboration. /The title compound was tested by ToxCast and/or Tox21 assays/[USEPAICSS Dashboard ApplicationAvailable from, as of November 16, 2017: http://actor.epa.gov/dashboard/] |
| Federal drinking water guidelines | EPA 200 ug/L |
| Personal protective equipment (PPE) | dust mask type N95 (US), Eyeshields, Faceshields, Gloves |
| Water hazard class (WGK) | 2 |
| TSCA inventory status | TSCA listed |
| RTECS number | DK9900000 |
| UN transport number | UN 1648 3/PG 2 |
| Customs code | 29349990 |
| Toxicity | LD50 in male, female rats (mg/kg): 383.2, 433.6 orally (Ugazio) |
| Risk statements (R) | 22-36-43-52/53-20/21/22-11 |
| Signal word | Warning |
| GHS pictogram | GHS07 |
| Hazard symbols | Xn,F |
| Safety statements (S) | 2-24-37-61-36-26-16 |
| Storage class | 11 - Combustible Solids |
| GHS hazard statements | H302-H317-H319-H412 |
| Hazard class | Acute Tox. 4 OralEye Irrit. 2Repr. 2Skin Sens. 1 |
| GHS precautionary statements | P261-P273-P280-P301+P312-P302+P352-P305+P351+P338 |
| Hazardous substances data | 25057-89-0(Hazardous Substances Data) |
Applications & Uses
Description
Bentazone is unique under these herbicides because it is the only compound that bears a sulfonyl group. A puzzle that is not solved yet is that bentazone is an excellent herbicide but has a very low pI50-value.
Uses
Herbicide.
Uses
Selective, contact, postemergence herbicide used to control a variety of annual and perennial broad-leaved weeds in most grass and legume crops.