Bis(diisopropylamino)chlorophosphine

HCID 2733425CAS 56183-63-2
Substructure searchFind similar structures

Basic information

Standard SMILES
CC(C)N(C(C)C)P(Cl)N(C(C)C)C(C)C
InChIKey
FEHUTHGOLLQBNW-UHFFFAOYSA-N
Molecular formula
C12H28ClN2P
Average molar mass
266.79 g/mol
Monoisotopic mass
266.1678636

Names & identifiers

Preferred name
Bis(diisopropylamino)chlorophosphine
IUPAC
N-[chloro-[di(propan-2-yl)amino]phosphanyl]-N-propan-2-ylpropan-2-amine
English name
BIS(DIISOPROPYLAMINO)CHLOROPHOSPHINE
Molecular formula
C12H28ClN2P
Molecular weight
266.79

Names & synonyms

Bis(diisopropylamino)chlorophosphine56183-63-2DTXSID00369907RefChem:569062DTXCID10320943628-718-5MFCD00061482N-[chloro-[di(propan-2-yl)amino]phosphanyl]-N-propan-2-ylpropan-2-aminePhosphorodiamidous chloride, tetrakis(1-methylethyl)-C12H28ClN2PSCHEMBL1117784bisdiisopropylaminochlorophosphine
Show more names
Bis(diisopropyamino)chlorophosphineChlorobis(N,N-diisopropylamino)phosphineSKL629Bis(diisopropylaminodiisopropylaMino)phosphineChlorbis(diisopropylamino)phosphanChloro-di-N-(diisopropyl)-phosphiteBIS(DI-I-PROPYLAMINO)CHLOROPHOSPHINE
FEHUTHGOLLQBNW-UHFFFAOYSA-NGCA18363Bis(di-isopropylamino)chlorophosphineChloro(bis(diisopropylamino))phosphaneAKOS015910528bis(N,N-diisopropylamino)chlorophosphinebis-(N,N-diisopropylamino)chlorophosphineBP-14118

Database identifiers

CAS
56183-63-2
PubChem CID
2733425
DTXSID
DTXSID00369907
EC Number
628-718-5
Nikkaji
J1.175.515A

Properties

Computed structural properties

XLogP
4.4
Topological polar surface area
6.5 Ų
Hydrogen bond donors
0
Hydrogen bond acceptors
2
Rotatable bonds
6
Heavy atoms
16

Physicochemical properties

Melting point
100 · 100-104 °C(lit.)
Boiling point
291 ℃ · 291℃
Flash point
130 ℃ · 130℃
storage temp.
Store under inert gas
form
Powder
pka
4.5 · 4.50±0.70(Predicted)

Safety & regulation

GHS classification

GHS Classification · 5 items

Danger

H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]；H318 (97.6%): Causes serious eye damage [Danger Serious eye damage/eye irritation]

P260, P264, P264+P265, P280, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P321, P363, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 42 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

Hazard information

Hazard Classes and CategoriesSkin Corr. 1B (100%)；Eye Dam. 1 (97.6%)

Safety data

PPE
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
wgk
3
ridadr
UN 3261 8/PG 1
hs_code
29310099
risk_code
14-34
Signal word
Danger

Chemistry & industry

Applications · 2 items

DescriptionBis(diisopropylamino)chlorophosphine is a white to off-white powder to crystalline organophosphorus compound, mainly used as an organic synthetic raw material or reaction reagent. It can be used in the synthesis of mixed phosphorothioate and methylenephosphine derivatives, etc. It is commonly used in chemical production and laboratory research.

UsesBis(diisopropylamino)chlorophosphine has been used in the synthesis of tert-butyl tetraisopropylphosphorodiamidite ligand for palladium-catalyzed Buchwald–Hartwig amination reaction.It is also can be used to synthesize:acyclic N-phosphonio imine catalyst for selective epoxidationsboryl-substituted methylenephosphonium derivatives

Upstream & downstream products

Suppliers50 total

绍兴赜军生物医药科技有限公司0575-82126188 15395856318
上海莉凯化工技术有限公司16628776521 · [email protected]
天津瑞德法莫科技有限公司13821803402 · [email protected]
Hong Kong Tiansheng New Material Trading Co., Ltd+8617320695765 · [email protected]
河南多贝化工有限公司0370-6999054 17550096163 · [email protected]

Related reactions

20 records
New reaction record

Linked notes

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