Magnesium, chloroethyl-

HCID 75432CAS 2386-64-3
Substructure searchFind similar structures

Basic information

Standard SMILES
[CH2-]C.[Cl-].[Mg+2]
InChIKey
ZWNJJACKPNTXHY-UHFFFAOYSA-M
Molecular formula
C2.H5.Cl.Mg
Average molar mass
88.82 g/mol

Overview

Ethylmagnesium chloride is an alkylmagnesium halide. It has a role as a Grignard reagent.

Names & identifiers

Preferred name
Magnesium, chloroethyl-
IUPAC
magnesium;ethane;chloride
English name
Ethylmagnesium chloride
Molecular formula
C2H5ClMg
Molecular weight
88.82

Names & synonyms

ethylmagnesium chloride2386-64-3ChloroethylmagnesiumMagnesium, chloroethyl-chloro(ethyl)magnesiumEINECS 219-206-9CHEBI:51239DTXSID40883839EC 219-206-9RefChem:800680DTXCID401023324219-206-9
Show more names
ethylmagnesium chloride solutionChlorethylmagnesiumEthylchloromagnesiumEthylMagnesiuM ChloridMagnesium ethyl chloride18%inTetrahydrofuran,ca.2mol/l)
ethylmagnesiumchloridemagnesium;ethane;chlorideEtMgClchloroethyl-magnesiuethyl magnesium chlorideChloridoethylmagnesiumMFCD00000472ethyl magnesiumchloride

Database identifiers

CAS
2386-64-3
PubChem CID
75432
DTXSID
DTXSID40883839
ChEBI
CHEBI:51239
EC Number
219-206-9

Properties

Computed structural properties

Topological polar surface area
0 Ų
Hydrogen bond donors
0
Hydrogen bond acceptors
2
Rotatable bonds
0
Heavy atoms
4

Experimental & physicochemical properties

Density0.978 @25 °C

Physicochemical properties

Boiling point
66 ℃ · 66℃
Density
1 g/mL · 1.00 g/mL at 20 °C
Flash point
1 °F · 1 °F
storage temp.
water-free area
form
Solution
color
Yellow to dark brown

Safety & regulation

GHS classification

GHS Classification · 4 items

Danger

H225 (60.4%): Highly Flammable liquid and vapor [Danger Flammable liquids]

P210, P223, P231+P232, P233, P240, P241, P242, P243, P260, P264, P264+P265, P280, P301+P330+P331, P302+P335+P334, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P317, P321, P363, P370+P378, P402+P404, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 111 reports by companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Hazard information

Regulatory Information · 2 items

REACH registered substance: Chloroethylmagnesium (EC: 219-206-9)

Magnesium, chloroethyl-: Does not have an individual approval but may be used under an appropriate group standard

Hazard Classes and CategoriesFlam. Liq. 2 (60.4%)

Safety & protection

Protective Action Criteria (PAC) · 3 items

1.2 [mg/m3]

13 [mg/m3]

79 [mg/m3]

Safety data

F
1-3-10
PPE
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
wgk
1
tsca
TSCA listed
ridadr
UN 3399 4.3/PG 1
hs_code
29319090

Chemistry & industry

Uses & manufacturing

General Manufacturing InformationMagnesium, chloroethyl-: ACTIVE
Applications · 2 items

UsesGrignard-type reactions.

UsesEthylmagnesium chloride solution can be used: In Cp2ZrCl2 catalyzed ethylcarboxylation of alkenes using carbon dioxide to corresponding carboxylic acids. In the preparation of cyclobutylmagnesium carbenoids by reacting with 1-chlorocyclobutyl p-tolyl sulfoxides.

Upstream & downstream products

Suppliers50 total

北京华美互利生物化工010-56205725 · [email protected]
梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
山东旭晨化工科技有限公司0533-15715337262 15715337262 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
湖北万得化工有限公司15377098680 15377098680 · [email protected]

Additional notes

DefinitionCHEBI:Ethylmagnesium chloride is an alkylmagnesium halide. It has a role as a Grignard reagent.

Related reactions

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