HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hydroxyamine hydrochloride → 5-(2,4-Dichlorophenyl)-2-furancarboxaldehyde Oxime
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hydroxyamine hydrochloride | HCID 443297 | — |
| Reactant | Sodium Acetate | HCID 517045 | — |
| Reactant | 5-(2,4-Dichlorophenyl)-2-furaldehyde | HCID 674998 | — |
| Solvent | Water | HCID 962 | — |
| Product | 5-(2,4-Dichlorophenyl)-2-furancarboxaldehyde Oxime | HCID 73164714 | — |
Reaction Steps
A mixture of 5-(2,4-dichlorophenyl)-2-furancarboxaldehyde (635 g, 2.63 moles), anhydrous sodium acetate (432 g, 5.26 moles), hydroxylamine hydrochloride (366 g, 5.26 moles), SDA #30 (9184 ml) and water (918 ml), was refluxed for 51/3 hours and allowed to stand overnight. The mixture was added to ice/H2O (42 liters), stirred 1 hour and filtered. The grayish-tan solid was washed with water (10 liters), filtered and dried at 65° to 660 g (98%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04336199 |
| Source dataset | uspto-grants-1982_06 |
| ORD ID | ord-f31b852d434643aaa384fb2fff829726 |
| Source note | uspto-grants-1982_06 |