HuagongsheHuagongshe Chemistry Print Report · For research reference only
Acetone → n-BUTYL 2-CYCLOPENTENYL ETHER
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Acetone | HCID 180 | — |
| Reactant | 1-Butanol | HCID 263 | — |
| Reactant | Acetic acid, cyclopent-2-en-1-yl ester | HCID 140735 | — |
| Catalyst | Tetrabutylammonium hydrogen sulfate | HCID 94433 | — |
| Solvent | Water | HCID 962 | — |
| Product | n-BUTYL 2-CYCLOPENTENYL ETHER | HCID 21318238 | — |
Reaction Steps
2-Cyclopentenyl acetate (0.30 g) and n-butanol (0.40 g) were mixed and stirred vigorously at 40° C. for 4 hours with a solution of 0.020 g of tetrabutylammonium hydrogen sulfate in 0.25 g of water. At the end of the reaction period acetone was added to give a single phase, and the solution was analyzed by gas chromatography using an Apiezon column programmed at 60°-220° C. Peaks for the cyclic compounds had the following relative areas.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04156097 |
| Source dataset | uspto-grants-1979_05 |
| ORD ID | ord-67c3d3b3b2a74cc1a960ddbf51202734 |
| Source note | uspto-grants-1979_05 |