HuagongsheHuagongshe Chemistry Print Report · For research reference only
m-Chloroperbenzoic acid → 11-methylene-3-methylsulfinyl-11H-s-triazolo[3,4-b][3]benzazepine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | m-Chloroperbenzoic acid | HCID 70297 | — |
| Reactant | 11-methylene-3-methylthio-11H-s-triazolo[3,4-b][3]benzazepine | HCID 21323409 | — |
| Product | 11-methylene-3-methylsulfinyl-11H-s-triazolo[3,4-b][3]benzazepine | HCID 21323367 | — |
Reaction Steps
By a procedure similar to that of Example 17, the reaction of 11-methylene-3-methylthio-11H-s-triazolo[3,4-b][3]benzazepine with m-chloroperbenzoic acid gave 11-methylene-3-methylsulfinyl-11H-s-triazolo[3,4-b][3]benzazepine as crystals. Recrystallization from ethyl acetate yielded colorless prisms, m.p. 140°-142° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04150139 |
| Source dataset | uspto-grants-1979_04 |
| ORD ID | ord-9ffaacf5506e43fda0f716845647efb3 |
| Source note | uspto-grants-1979_04 |