Acetone → Benzenamine, 5-chloro-2-(4-chlorophenoxy)-

HRID 27624

Reaction equation

HRID 27624 reaction equation
ClC1C=CC([C:8]2[C:9]([N+:33]([O-])=O)=[C:10]([O:15][C:16]3[CH:21]=[CH:20][C:19]([Cl:22])=[C:18](C4C=CC(Cl)=CC=4)[C:17]=3[N+]([O-])=O)[CH:11]=[CH:12][C:13]=2[Cl:14])=CC=1.CC(C)=O.S(S([O-])=O)([O-])=O.[Na+].[Na+]>O>[Cl:14][C:13]1[CH:12]=[CH:11][C:10]([O:15][C:16]2[CH:21]=[CH:20][C:19]([Cl:22])=[CH:18][CH:17]=2)=[C:9]([CH:8]=1)[NH2:33]

Participants

5

Reactant 3

HCID 180AcetoneHCID 24489Sodium DithioniteHCID 57255352HCID 57255352, compound

Product 1

HCID 67135Benzenamine, 5-chloro-2-(4-chlorophenoxy)-

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

A 140 g. portion of the above nitro derivative in 1400 ml. of acetone is reduced with 560 g. of sodium hydrosulfite in 1400 ml. of water as described in Example 1, giving 5-chloro-2-(p-chlorophenoxy)aniline.

Sources & evidence

ORD record
ord-60fa2b14f13f4a0c8c9995497ce85fd2
Source dataset
uspto-grants-1980_09
Patent number
US04221714

Linked notes

Loading…