HuagongsheHuagongshe Chemistry Print Report · For research reference only
Isoprene → 3-Cyclohexene-1-methanol, 4-methyl-
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Isoprene | HCID 6557 | — |
| Reactant | Acrolein | HCID 7847 | — |
| Product | 3-Cyclohexene-1-methanol, 4-methyl- | HCID 564672 | — |
Reaction Steps
According to the well known Diels-Alder Reaction, using isoprene and acrolein as raw materials, 4-methyl-3-cyclohexenyl aldehyde was synthesized. The reaction was conducted under the conditions described in the literary documents of J. Amer, Chem. Soc., 119, 15, 1997, 3507-3512; and Tetrahedron Lett., 40, 32, 1999, 5817-5822. Subsequently, the compound was reduced to obtain 4-methyl-3-cyclohexenylmethanol at a high yield.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07429622B2 |
| Source dataset | uspto-grants-2008_09 |
| ORD ID | ord-7d1005021b344960abba0f2bfa216f2f |
| Source note | uspto-grants-2008_09 |