HuagongsheHuagongshe Chemistry Print Report · For research reference only
Diethyl butylmalonate → 4-n-Butyl-1-[4-(3-methoxyprop-1-ynyl)phenyl]-3-trifluoromethyl-2,6,7-trioxabicyclo[2,2,2]octane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Diethyl butylmalonate | HCID 67244 | — |
| Reactant | 1-[4-(3-Methoxyprop-1-ynyl)phenyl]-4-n-propyl-3-trifluoromethyl-2,6,7-trioxabicyclo[2,2,2]octane | HCID 15021984 | — |
| Product | 4-n-Butyl-1-[4-(3-methoxyprop-1-ynyl)phenyl]-3-trifluoromethyl-2,6,7-trioxabicyclo[2,2,2]octane | HCID 15021990 | — |
Reaction Steps
4-n-Butyl-1-[4-(3-methoxyprop-1ynyl)phenyl]-3-trifluoromethyl-2,6,7-trioxabicyclo[2,2,2]octane was prepared from diethyl n-butyl-malonate in a manner analogous to the synthesis of 1-[4-(3-methoxyprop-1-ynyl)phenyl]-4-n-propyl-3-trifluoromethyl-2,6,7-trioxabicyclo[2,2,2]octane.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05157029 |
| Source dataset | uspto-grants-1992_10 |
| ORD ID | ord-6e0f4516535440078c831e276068a63f |
| Source note | uspto-grants-1992_10 |