Potassium Hydroxide → HCID 13043902、化合物

HRID 1065777

反応式

HRID 1065777 の反応式
[NH2:1][C:2]1[C:7]([Cl:8])=[C:6]([CH3:9])[C:5]([Cl:10])=[C:4]([CH3:11])[N:3]=1.[OH-].[K+].[N+:14]([C:17]1[CH:22]=[C:21]([N+:23]([O-:25])=[O:24])[CH:20]=[C:19]([C:26]([F:29])([F:28])[F:27])[C:18]=1Cl)([O-:16])=[O:15]>CN(C)C=O>[Cl:8][C:7]1[C:2]([NH:1][C:18]2[C:19]([C:26]([F:28])([F:29])[F:27])=[CH:20][C:21]([N+:23]([O-:25])=[O:24])=[CH:22][C:17]=2[N+:14]([O-:16])=[O:15])=[N:3][C:4]([CH3:11])=[C:5]([Cl:10])[C:6]=1[CH3:9]

参加物

5

反応物 3

HCID 14797Potassium HydroxideHCID 67851Benzene, 2-chloro-1,5-dinitro-3-(trifluoromethyl)-HCID 122510103,5-Dichloro-4,6-dimethylpyridin-2-amine

生成物 1

HCID 13043902HCID 13043902、化合物

試薬・触媒・溶媒 1

HCID 6228Dimethylformamide溶媒2 回

実験手順

In 20 ml. of dimethylformamide, 1.9 g. of 2-amino-3,5-dichloro-4,6-dimethylpyridine was dissolved and 0.7 g. of powdery potassium hydroxide was gradually added with stirring and a solution of 2.7 g. of 2,4-dinitro-6-trifluoromethylchlorobenzene in 10 ml. of dimethylformamide was added dropwise at room temperature to react them for about 10 hours. The reaction mixture was treated as the process of Preparation No. 7 to obtain 1.6 g. of the object compound having the melting point of 131° to 133° C.

後処理

  1. customto react them for about 10 hours
  2. additionThe reaction mixture was treated as the process of Preparation No
  3. custom7 to obtain 1.6 g

出典と根拠

ORDレコード
ord-1c7e097d51ff48ea8a22f98e6342a625
出典データセット
uspto-grants-1982_05
特許番号
US04331670

関連ノート

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