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N-Methylbenzothiazol-2-amine → 3-Methyl-1,3-benzothiazol-2(3H)-imine
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | N-Methylbenzothiazol-2-amine | HCID 28160 | — |
| 反応物 | 4-Thioureidoanisole | HCID 667549 | — |
| 反応物 | 1-Methyl-3-phenylthiourea | HCID 698294 | — |
| 反応物 | 1-Methyl-1-phenylthiourea | HCID 723631 | — |
| 生成物 | 3-Methyl-1,3-benzothiazol-2(3H)-imine | HCID 84642 | — |
反応手順
When using, instead of 4-methoxyphenyl-thiourea of Examples 89 and 90, equivalent amounts of N-phenyl-N'-methyl-thiourea or N-phenyl-N-methyl-thiourea, the other conditions remaining the same, 2-methylamino-benzthiazole (m.p. 137° C.) or 3-methyl-2-imino-benzthiazoline (m.p. 122°) is obtained in an equally good yield and in a high purity.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04252963 |
| 出典データセット | uspto-grants-1981_02 |
| ORD ID | ord-d2fea834efa7435185c3ef5a025ed5be |
| 出典メモ | uspto-grants-1981_02 |