関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Water | HCID 962 | — |
| 反応物 | 4,7-Methano-5H-inden-5-one, octahydro- | HCID 96509 | — |
| 反応物 | Sodium Methoxide | HCID 10942334 | — |
| 溶媒 | Cyclohexane | HCID 8078 | — |
| 生成物 | 9-(4-Formylbenzylidene)-8-ketotricyclo[5.2.1.02,6]decane | HCID 54022151 | — |
反応手順
A suspension of 40 mmol (6.3 g) of 8-ketotricyclo[5.2.1.02,6 ]decane and 60 mmol of sodium methoxide (11 g of a 30% solution) in 50 ml of cyclohexane are stirred at 50° C. for 30 minutes. 50 mmol (9.0 g) of terephthalaldehyde monodimethyl acetal are then added dropwise and the mixture is refluxed for 1 hour. It is then cooled to room temperature and 100 ml of water are added.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US05677314 |
|---|
| 出典データセット | uspto-grants-1997_10 |
|---|
| ORD ID | ord-65eb37158b154bfcbc862fe249bc7eda |
|---|
| 出典メモ | uspto-grants-1997_10 |
|---|
