化工社化工社 化学情報印刷レポート · 研究参考用
1-Acetylcyclohexene → 3-Amino-4a,5,6,7,8,8a-hexahydro-4H-naphthalen-1-one
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 1-Acetylcyclohexene | HCID 13612 | — |
| 反応物 | Ammonium Acetate | HCID 517165 | — |
| 反応物 | 5-(4-(Dimethylamino)phenyl)-1,3-cyclohexanedione | HCID 730117 | — |
| 生成物 | 3-Amino-4a,5,6,7,8,8a-hexahydro-4H-naphthalen-1-one | HCID 57883327 | — |
反応手順
In analogy to (Baraldi, P. G.; Simoni, D.; Manfredini, S.; Synthesis 1983, (11) 902-903) hexahydro-naphthalene-1,3-dione (prepared from 1-cyclohex-1-enyl-ethanone according to (Chuang; Tien. Chem. Ber. 1936; 69; 25-29) was reacted with ammonium acetate to give the title compound as a colorless solid.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US07598384B2 |
| 出典データセット | uspto-grants-2009_10 |
| ORD ID | ord-8bf160331b8c4914824225b871c6041a |
| 出典メモ | uspto-grants-2009_10 |