関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Benzyl azide | HCID 12152 | — |
| 反応物 | Tributyl(2-phenylethynyl)stannane | HCID 630640 | — |
| 生成物 | HCID 68738217 | HCID 68738217 | — |
反応手順
Phenylethynyltri-n-butyltin (8.25 g, 21.1 mmol) and benzyl azide (2.3 mL, 18.4 mmol) were combined and heated to 150° C. overnight. The mixture was purified by silica gel chromatography eluting with a gradient of 5-40% ethyl acetate in hexanes to afford the title compound. MS (ESI+) m/z 526.3 (M+H)+.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US08648069B2 |
|---|
| 出典データセット | uspto-grants-2014_02 |
|---|
| ORD ID | ord-188aec90da8d407986ced84dd7f2e5c8 |
|---|
| 出典メモ | uspto-grants-2014_02 |
|---|
