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Acetone → n-BUTYL 2-CYCLOPENTENYL ETHER
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Acetone | HCID 180 | — |
| 反応物 | 1-Butanol | HCID 263 | — |
| 反応物 | Acetic acid, cyclopent-2-en-1-yl ester | HCID 140735 | — |
| 触媒 | Tetrabutylammonium hydrogen sulfate | HCID 94433 | — |
| 溶媒 | Water | HCID 962 | — |
| 生成物 | n-BUTYL 2-CYCLOPENTENYL ETHER | HCID 21318238 | — |
反応手順
2-Cyclopentenyl acetate (0.30 g) and n-butanol (0.40 g) were mixed and stirred vigorously at 40° C. for 4 hours with a solution of 0.020 g of tetrabutylammonium hydrogen sulfate in 0.25 g of water. At the end of the reaction period acetone was added to give a single phase, and the solution was analyzed by gas chromatography using an Apiezon column programmed at 60°-220° C. Peaks for the cyclic compounds had the following relative areas.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04156097 |
| 出典データセット | uspto-grants-1979_05 |
| ORD ID | ord-67c3d3b3b2a74cc1a960ddbf51202734 |
| 出典メモ | uspto-grants-1979_05 |